Interparticle interactions and rheological signatures of Ti3C2Tz MXene dispersions

dc.authorid0000-0002-0671-208Xen_US
dc.contributor.authorTezel, Güler Bengüsu
dc.contributor.authorArole, Kailash
dc.contributor.authorHolta, Dustin E.
dc.contributor.authorRadovic, Miladin
dc.contributor.authorGreen, Micah J.
dc.date.accessioned2023-05-17T08:42:07Z
dc.date.available2023-05-17T08:42:07Z
dc.date.issued2022en_US
dc.departmentBAİBÜ, Mühendislik Fakültesi, Kimya Mühendisliği Bölümüen_US
dc.description.abstractHypothesis: We hypothesize that dispersed Ti3C2Tz MXene particle interactions are reflected in the bulk viscoelastic properties of the dispersions and can be analyzed using classical colloidal theory for anisotropic particles. The relevant kinetic theory for Brownian anisotropic particles is given by the Doi and Edwards (D-E) Model, and the Maxwell Model is used to fit the relaxation times as a function of frequency. Such behavior is relevant to a variety of MXene processing techniques, particularly printing and coating. Experiments: Small oscillatory shear tests were performed for dilute Ti3C2Tz MXene aqueous dispersions as a function of their concentration and temperature. Scanning electron microscopy (SEM), X-ray Diffraction (XRD), Atomic Force Microscopy (AFM), f potential measurements, Dynamic Light Scattering (DLS) were used to characterize the Ti3C2Tz MXene nanoparticles. Findings: Ti3C2Tz dispersions show gel-like and viscous-like behavior at low and high temperatures, respectively. Experimental relaxation times fitted to the Maxwell model are found to be close to the theoretical values. However, at high temperatures, relaxation time values differ due to the inter-particle interactions, even in the dilute concentration regime. For Ti3C2Tz dispersions, aggregation, and clustering can have dramatic consequences for dispersion rheology, including gelation, as the sample transitions from liquid-like to solid-like behavior.en_US
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK) 2219-International Postdoctoral Research Fellowship Program for Turkish Citizens(Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK))en_US
dc.identifier.citationTezel, G. B., Arole, K., Holta, D. E., Radovic, M., & Green, M. J. (2022). Interparticle interactions and rheological signatures of Ti3C2Tz MXene dispersions. Journal of Colloid and Interface Science, 605, 120-128. doi:10.1016/j.jcis.2021.07.068en_US
dc.identifier.doi10.1016/j.jcis.2021.07.068
dc.identifier.endpage128en_US
dc.identifier.issn0021-9797
dc.identifier.issn1095-7103
dc.identifier.pmid34311306en_US
dc.identifier.scopus2-s2.0-85111034302en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage120en_US
dc.identifier.urihttp://dx.doi.org/10.1016/j.jcis.2021.07.068
dc.identifier.urihttps://hdl.handle.net/20.500.12491/10902
dc.identifier.volume605en_US
dc.identifier.wosWOS:000703555200002en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.institutionauthorTezel, Güler Bengüsu
dc.language.isoenen_US
dc.publisherACADEMIC PRESS INC ELSEVIER SCIENCEen_US
dc.relation.ispartofJournal of Colloid and Interface Scienceen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectMXeneen_US
dc.subjectTi3C2Tzen_US
dc.subjectRheologyen_US
dc.subjectNanosheetsen_US
dc.titleInterparticle interactions and rheological signatures of Ti3C2Tz MXene dispersionsen_US
dc.typeArticleen_US

Dosyalar

Orijinal paket
Listeleniyor 1 - 1 / 1
Küçük Resim Yok
İsim:
guler-bengusu-tezel.pdf
Boyut:
1.59 MB
Biçim:
Adobe Portable Document Format
Açıklama:
Tam Metin/Full Text
Lisans paketi
Listeleniyor 1 - 1 / 1
Küçük Resim Yok
İsim:
license.txt
Boyut:
1.44 KB
Biçim:
Item-specific license agreed upon to submission
Açıklama: