Volumetric properties and viscosities for 1-Ethyl-3-methylimidazolium ethyl sulfate and ethylene glycol binary mixture from 293.15 K to 343.15 K at atmospheric pressure

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dc.authorid0000-0003-3947-5698en_US
dc.authorid0000-0002-3690-7929en_US
dc.authorid0000-0002-7658-5194en_US
dc.contributor.authorAltun, Aycan
dc.contributor.authorŞara, Osman Nuri
dc.contributor.authorPekdemir, Turgay
dc.date.accessioned2023-09-28T09:45:19Z
dc.date.available2023-09-28T09:45:19Z
dc.date.issued2023en_US
dc.departmentBAİBÜ, Mühendislik Fakültesi, Kimya Mühendisliği Bölümüen_US
dc.description.abstractThis study presents the results from the measurements and further analysis of densities and viscosities of pure 1-ethyl-3-methylimidazolium ethyl sulfate, EMISE, and its binary mixtures with ethylene glycol, EG, over the entire composition range. Measured at atmospheric pressure from 293.15 to 343.15 K. A first-order polynomial equation was fitted to experimental density values of the EMISE + EG binary mixtures, whereas Vogel-Fulcher-Tammann (VFT) equation was used to fit viscosity data. Volumetric and excess properties have been determined. The excess molar volumes and viscosity deviations were correlated by the Redlich-Kister polynomial equation. Additionally, several selected semi-empirical viscosity models for EMISE + EG binary mixtures were tested, and coefficients were obtained. The thermal expansion coefficients of EMISE + EG binary mixtures were calculated. The intermolecular interactions between components were discussed. The results showed that in addition to the intermolecular interactions between components, packing effects due to the molecular size caused changes in properties.en_US
dc.description.sponsorshipBursa Technical University (Turkey) Scientific Research Project Grant, (BAP in Turkish) [210Y005]
dc.identifier.citationAltun, A., Şara, O. N., & Pekdemir, T. (2023). Volumetric Properties and Viscosities for 1-Ethyl-3-methylimidazolium Ethyl Sulfate and Ethylene Glycol Binary Mixture from 293.15 K to 343.15 K at Atmospheric Pressure. Journal of Solution Chemistry, 52(5), 530-550.en_US
dc.identifier.doi10.1007/s10953-023-01246-7
dc.identifier.endpage550en_US
dc.identifier.issn0095-9782
dc.identifier.issn1572-8927
dc.identifier.issue5en_US
dc.identifier.scopus2-s2.0-85148359386en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage530en_US
dc.identifier.urihttp://dx.doi.org/10.1007/s10953-023-01246-7
dc.identifier.urihttps://hdl.handle.net/20.500.12491/11757
dc.identifier.volume52en_US
dc.identifier.wosWOS:000936204200003en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorPekdemir, Turgay
dc.language.isoenen_US
dc.publisherSpringer/Plenum Publishersen_US
dc.relation.ispartofJournal of Solution Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject1-Ethyl-3-Methylimidazolium Ethyl Sulfateen_US
dc.subjectLonic Liquiden_US
dc.subjectEthylene Glycolen_US
dc.subjectDensityen_US
dc.subjectViscosityen_US
dc.subjectExcess Propertiesen_US
dc.titleVolumetric properties and viscosities for 1-Ethyl-3-methylimidazolium ethyl sulfate and ethylene glycol binary mixture from 293.15 K to 343.15 K at atmospheric pressureen_US
dc.typeArticleen_US

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