Volumetric properties and viscosities for 1-Ethyl-3-methylimidazolium ethyl sulfate and ethylene glycol binary mixture from 293.15 K to 343.15 K at atmospheric pressure
Yükleniyor...
Dosyalar
Tarih
2023
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Springer/Plenum Publishers
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
This study presents the results from the measurements and further analysis of densities and viscosities of pure 1-ethyl-3-methylimidazolium ethyl sulfate, EMISE, and its binary mixtures with ethylene glycol, EG, over the entire composition range. Measured at atmospheric pressure from 293.15 to 343.15 K. A first-order polynomial equation was fitted to experimental density values of the EMISE + EG binary mixtures, whereas Vogel-Fulcher-Tammann (VFT) equation was used to fit viscosity data. Volumetric and excess properties have been determined. The excess molar volumes and viscosity deviations were correlated by the Redlich-Kister polynomial equation. Additionally, several selected semi-empirical viscosity models for EMISE + EG binary mixtures were tested, and coefficients were obtained. The thermal expansion coefficients of EMISE + EG binary mixtures were calculated. The intermolecular interactions between components were discussed. The results showed that in addition to the intermolecular interactions between components, packing effects due to the molecular size caused changes in properties.
Açıklama
Anahtar Kelimeler
1-Ethyl-3-Methylimidazolium Ethyl Sulfate, Lonic Liquid, Ethylene Glycol, Density, Viscosity, Excess Properties
Kaynak
Journal of Solution Chemistry
WoS Q Değeri
Q4
Scopus Q Değeri
Q3
Cilt
52
Sayı
5
Künye
Altun, A., Şara, O. N., & Pekdemir, T. (2023). Volumetric Properties and Viscosities for 1-Ethyl-3-methylimidazolium Ethyl Sulfate and Ethylene Glycol Binary Mixture from 293.15 K to 343.15 K at Atmospheric Pressure. Journal of Solution Chemistry, 52(5), 530-550.
