Thermal behaviors, combustion mechanisms, evolved gasses, and ash analysis of spent potlining for a hazardous waste management
dc.authorid | 0000-0001-6841-6457 | |
dc.authorid | 0000-0002-4699-4595 | |
dc.contributor.author | Sun, Guang | |
dc.contributor.author | Zhang, Gang | |
dc.contributor.author | Liu, Jingyong | |
dc.contributor.author | Evrendilek, Deniz Eren | |
dc.contributor.author | Büyükada, Musa | |
dc.date.accessioned | 2021-06-23T18:57:00Z | |
dc.date.available | 2021-06-23T18:57:00Z | |
dc.date.issued | 2021 | |
dc.department | BAİBÜ, Mühendislik Fakültesi, Kimya Mühendisliği Bölümü | en_US |
dc.description.abstract | An unavoidable but reusable waste so as to enhance a more circular waste utilization has been spent potlining (SPL) generated by the aluminum industry. The combustion mechanisms, evolved gasses, and ash properties of SPL were characterized dynamically in response to the elevated temperature and heating rates. Differential scanning calorimetric (DSC) results indicated an exothermic reaction behavior probably able to meet the energy needs of various industrial applications. The reaction mechanisms for the SPL combustion were best described using the 1.5-, 3- and 2.5-order reaction models. Fluoride volatilization rate of the flue gas was estimated at 2.24%. The SPL combustion emitted CO2, HNCO, NO, and NO2 but SOx. The joint optimization of remaining mass, derivative thermogravimetry, and derivative DSC was achieved with the optimal temperature and heating rate combination of 783.5 °C, and 5 °C/min, respectively. Interaction between temperature and heating rate exerted the strongest and weakest impact on DSC and remaining mass, respectively. The fluorine mainly as the formation of substantial NaF and CaF2 in the residual ash. Besides, the composition and effect of environment of residual solid were evaluated. The ash slagging tendency and its mineral deposition mechanisms were elucidated in terms of turning SPL waste into a benign input to a circular waste utilization. | en_US |
dc.description.sponsorship | TDQN2019006 2019507140211 National Natural Science Foundation of China, NSFC: 22006015, 51978175 | en_US |
dc.description.sponsorship | This work was supported by the National Natural Science Foundation of China (Nos. 51978175 , 22006015 ), the Social Science and Technology Development Project of Dongguan (No. 2019507140211 ), and the Scientific Research Youth Team of Dongguan University of Technology (No. TDQN2019006 ). | en_US |
dc.identifier.doi | 10.1016/j.jes.2021.02.003 | |
dc.identifier.endpage | 137 | en_US |
dc.identifier.issn | 1001-0742 | |
dc.identifier.pmid | 34412775 | en_US |
dc.identifier.scopus | 2-s2.0-85100624961 | en_US |
dc.identifier.scopusquality | Q1 | en_US |
dc.identifier.startpage | 124 | en_US |
dc.identifier.uri | https://doi.org/10.1016/j.jes.2021.02.003 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12491/5113 | |
dc.identifier.volume | 107 | en_US |
dc.identifier.wos | WOS:000687721400011 | en_US |
dc.identifier.wosquality | Q1 | en_US |
dc.indekslendigikaynak | Web of Science | en_US |
dc.indekslendigikaynak | Scopus | en_US |
dc.indekslendigikaynak | PubMed | en_US |
dc.institutionauthor | Büyükada, Musa | |
dc.language.iso | en | en_US |
dc.publisher | Chinese Academy of Sciences | en_US |
dc.relation.ispartof | Journal of Environmental Sciences (China) | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Gas Emission | en_US |
dc.subject | Heat Release | en_US |
dc.subject | Reaction Mechanism | en_US |
dc.subject | Spent Potlining | en_US |
dc.subject | Thermal Decomposition | en_US |
dc.title | Thermal behaviors, combustion mechanisms, evolved gasses, and ash analysis of spent potlining for a hazardous waste management | en_US |
dc.type | Article | en_US |
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