Pyrolytic behaviors, kinetics, decomposition mechanisms, product distributions and joint optimization of Lentinus edodes stipe

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dc.authorid0000-0001-5555-7509en_US
dc.authorid0000-0001-6841-6457en_US
dc.authorid0000-0003-1099-4363en_US
dc.contributor.authorZou, Huihuang
dc.contributor.authorZhang, Junhui
dc.contributor.authorLiu, Jingyong
dc.contributor.authorBüyükada, Musa
dc.contributor.authorEvrendilek, Fatih
dc.contributor.authorLiang, Guanjie
dc.date.accessioned2021-06-23T19:54:11Z
dc.date.available2021-06-23T19:54:11Z
dc.date.issued2020
dc.departmentBAİBÜ, Mühendislik Fakültesi, Kimya Mühendisliği Bölümüen_US
dc.description.abstractThe pyrolytic behaviors, kinetics, decomposition mechanisms and product distributions and joint optimization of Lentinus edodes stipe (LES) were quantified. Its main pyrolysis stages (the decomposition of hemicellulose) occurred between 200 and 400 degrees C. Random nucleation and nuclei growth (A(0.91)), and orders of reaction (F-1.6 and F-2.1) best explained the three sub-stages of the LES pyrolysis mechanism, respectively. The gas emissions were in good agreement with pyrolysis behavior. The main distributions of the pyrolytic products were classified into the 12 types of acids, alcohols, aldehydes, ketones, esters, phenols, glucopyranoside, aliphatic hydrocarbons, furans, aromatic hydrocarbons, N-heterocyclic substances, and N-containing substances. Cellobiose was found as pyrolytic product during 400 and 600 degrees C. For economic and practical reasons, the target functions of the four responses for the LES pyrolysis were jointly best optimized combining the temperature of 550 degrees C and the heating rate of 12.5 degrees C/min. This study offers theoretical and practical insights into the pyrolysis performance and products of LES or similar second-generation feedstocks in a thermal reactor.en_US
dc.identifier.doi10.1016/j.enconman.2020.112858
dc.identifier.issn0196-8904
dc.identifier.issn1879-2227
dc.identifier.scopus2-s2.0-85083589495en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.urihttps://doi.org/10.1016/j.enconman.2020.112858
dc.identifier.urihttps://hdl.handle.net/20.500.12491/10453
dc.identifier.volume213en_US
dc.identifier.wosWOS:000534066300041en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorBüyükada, Musa
dc.institutionauthorEvrendilek, Fatih
dc.language.isoenen_US
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.ispartofEnergy Conversion And Managementen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectPyrolysisen_US
dc.subjectLentinus Edodes Stipeen_US
dc.subjectTG-FTIRen_US
dc.subjectMaster-plotsen_US
dc.subjectPy-GC/MSen_US
dc.titlePyrolytic behaviors, kinetics, decomposition mechanisms, product distributions and joint optimization of Lentinus edodes stipeen_US
dc.typeArticleen_US

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