Synthesis, crystal structure and magnetic behaviour of a mononuclear Fe(III) - schiff base metal complex
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Dosyalar
Tarih
2006
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Oldenbourg Verlag
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
A complex from Fe(II) and a hexa-dentate linear ligand containing O2N4 donor atoms were prepared and the structure enlightened with X-ray diffraction. The Fe(II) ion in the complex was seen to be oxidized to form a Fe(III) complex, [C20H24Cl3N4O2]Fe and the three chloride ions were situated at a distance of Fe...Cl(1) 3.976(5), Fe... Cl(2) 4.479(3) and Fe... Cl(3) 7.509(4) (A) over circle outside the coordination sphere. The Fe(III) ion has an octahedral coordination sphere and as expected the two oxygen donor atoms are coordinated in a -cis position. The Fe-O, Fe-N-imin and Fe-N-amine distances are 1.880(3) (A) over circle, 1.931(4) (A) over circle and 2.004(4) (A) over circle, respectively.
Açıklama
Anahtar Kelimeler
Fe(III) Metal Complex, Schiff Bases, X-ray Diffiraction, Crystal Structure ;Analysis
Kaynak
Zeitschrift Fur Kristallographie
WoS Q Değeri
Q2
Scopus Q Değeri
N/A
Cilt
221
Sayı
4
