Synthesis of novel dimeric subphthalocyanines via azide-alkyne Huisgen 1,3-dipolar cycloaddition and palladium-catalyzed Glaser-Hay coupling reactions

dc.authorid0000-0001-9258-1866en_US
dc.authorid0000-0003-4552-1910
dc.contributor.authorGöktuğ, Özge
dc.contributor.authorGöl, Cem
dc.contributor.authorDurmuş, Mahmut
dc.date.accessioned2021-06-23T19:45:43Z
dc.date.available2021-06-23T19:45:43Z
dc.date.issued2017
dc.departmentBAİBÜ, Rektörlük, Yenilikçi Gıda Teknolojileri Geliştirme Uygulama ve Araştırma Merkezien_US
dc.description.abstractIn this study, the monomeric subphthalocyanines bearing azido (2) and terminal ethynyl (3) groups were synthesized. These subphthalocyanines were converted to their dimeric derivatives using azide-alkyne Huisgen cycloaddition and palladium-catalyzed Glaser-Hay coupling reactions subphthalocyanine (4) and (5), respectively. The novel subphthalocyanines were fully characterized by elemental analysis and general spectroscopic methods such as MALDI-TOF mass, FT-IR, UV-vis and H-1-NMR. All synthesized subphthalocyanines showed quite good solubility in the most of common organic solvents. The fluorescence measurements were conducted for these subphthalocyanines to estimate their fluorescence quantum yields. The singlet oxygen generation abilities were also examined to investigate their photosensitizer properties.en_US
dc.identifier.doi10.1142/S108842461750050X
dc.identifier.endpage546en_US
dc.identifier.issn1088-4246
dc.identifier.issn1099-1409
dc.identifier.issue7-8en_US
dc.identifier.scopus2-s2.0-85029222350en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage539en_US
dc.identifier.urihttps://doi.org/10.1142/S108842461750050X
dc.identifier.urihttps://hdl.handle.net/20.500.12491/9198
dc.identifier.volume21en_US
dc.identifier.wosWOS:000410532700009en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorGöl, Cem
dc.language.isoenen_US
dc.publisherWorld Sci Publ Co Incen_US
dc.relation.ispartofJournal Of Porphyrins And Phthalocyaninesen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectSubphthalocyaninen_US
dc.subjectBoronen_US
dc.subjectSinglet Oxygenen_US
dc.subjectFluorescenceen_US
dc.subjectPhotosensitizeren_US
dc.titleSynthesis of novel dimeric subphthalocyanines via azide-alkyne Huisgen 1,3-dipolar cycloaddition and palladium-catalyzed Glaser-Hay coupling reactionsen_US
dc.typeArticleen_US

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