Industrial symbiosis: CO2 utilization by producing disodium octaborate tetrahydrate and baking soda from borax

Basit Öğe Kaydı
dc.authorid0000-0002-8574-1056en_US
dc.authorid0000-0003-3355-8222en_US
dc.authorid0000-0002-7658-5194en_US
dc.authorid0000-0003-1258-2282en_US
dc.contributor.authorÇopur, Mehmet
dc.contributor.authorŞenol, Ayşe Merve
dc.contributor.authorPekdemir, Turgay
dc.contributor.authorOnganer, Yavuz
dc.date.accessioned2024-07-30T13:33:46Z
dc.date.available2024-07-30T13:33:46Z
dc.date.issued2023en_US
dc.departmentBAİBÜ, Mühendislik Fakültesi, Kimya Mühendisliği Bölümüen_US
dc.descriptionThis work was supportedby a grant from the Scientific Research Projects funding Scheme of Ataturk University, Erzurum, Turkiye [grant number: 2010/218].en_US
dc.description.abstractThis paper proposesa novel method for CO2 capture,utilization, and sequestration (CCUS) with borax producing disodiumoctaborate tetrahydrate (Na2O & BULL;4(B2O3)& BULL;4H(2)O & EQUIV; Na2B8O13 & BULL;4H(2)O, DSOBTH) equivalent boron compoundsand sodium bicarbonate (NaHCO3). We tested the performanceof this method experimentally using aqueous ammonium (NH4 (+)) solutions in a pressurized reactor (1 L) continuouslypurged with pure (99.9%) CO2. Experimental parameters werechanged as temperature (T), 45-65 & DEG;C; solid-to-liquidratio (SLR), 0.69-0.92 g/mL; reaction time (t), 30-60 min; pressure (P), 5-30 bar;NH3 concentration (AC) 2.82-5.65 M; and steeringspeed (SS), 500 rpm. The results showed that P and T were highly influential on the performance. The best conditionsfor CO2 utilization were found as P =20 bar; T = 60 & DEG;C; SLR = 0.77 g/ml; t = 50 min; and AC = 4.76 M. Per ton of tincal, under theseconditions, produced were 0.274 ton of DSOBTH (& SIM;67% B2O3), 0.216 ton of NaHCO3 (& SIM;95% purity),0.386 ton of avoided boric acid, and 0.417 ton of avoided CO2. The total potential added value can be about $1100/ton of tincal.en_US
dc.description.sponsorshipAtaturk University, Erzurum, Turkiye [2010/218]en_US
dc.identifier.citationÇopur, M., Şenol, A. M., Pekdemir, T., & Onganer, Y. (2023). Industrial Symbiosis: CO2 Utilization by Producing Disodium Octaborate Tetrahydrate and Baking Soda from Borax. Industrial & Engineering Chemistry Research, 62(34), 13340-13354.en_US
dc.identifier.doi10.1021/acs.iecr.3c01095
dc.identifier.endpage13354en_US
dc.identifier.issn0888-5885
dc.identifier.issn1520-5045
dc.identifier.scopus2-s2.0-85169311659en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage13340en_US
dc.identifier.urihttp://dx.doi.org/10.1021/acs.iecr.3c01095
dc.identifier.urihttps://hdl.handle.net/20.500.12491/12291
dc.identifier.volume62en_US
dc.identifier.wosWOS:001051338400001en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorPekdemir, Turgay
dc.language.isoenen_US
dc.publisherAmer Chemical Socen_US
dc.relation.ispartofIndustrial & Engineering Chemistry Researchen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectBoric-Aciden_US
dc.subjectOptimum Conditionsen_US
dc.subjectCarbon-Dioxideen_US
dc.subjectMineral Carbonationen_US
dc.subjectSodium Pentaborateen_US
dc.subjectFlue-Gasen_US
dc.subjectCaptureen_US
dc.titleIndustrial symbiosis: CO2 utilization by producing disodium octaborate tetrahydrate and baking soda from boraxen_US
dc.typeArticleen_US

Dosyalar

Orijinal paket
Listeleniyor 1 - 1 / 1
Küçük Resim
İsim:
mehmet-copur.pdf
Boyut:
6.68 MB
Biçim:
Adobe Portable Document Format
Açıklama:
Tam metin/Full text
İndir
Lisans paketi
Listeleniyor 1 - 1 / 1
Küçük Resim Yok
İsim:
license.txt
Boyut:
1.44 KB
Biçim:
Item-specific license agreed upon to submission
Açıklama:
İndir

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Kimya Mühendisliği Bölümü Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu