Sources of polycyclic hydrocarbons and pesticides in soluble fraction of deposition samples in Kocaeli, Turkey

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dc.authorid0000-0002-0107-0110
dc.authorid0000-0002-5760-8653
dc.contributor.authorBinici, Burcu
dc.contributor.authorKarakaş, Serpil Yenisoy
dc.contributor.authorBilsel, Mine
dc.contributor.authorHilmioğlu, Nilüfer Durmaz
dc.date.accessioned2021-06-23T19:36:22Z
dc.date.available2021-06-23T19:36:22Z
dc.date.issued2014
dc.departmentBAİBÜ, Fen Edebiyat Fakültesi, Kimya Bölümüen_US
dc.description.abstractA wet-dry deposition sampler was located at The Scientific and Technological Research Council of Turkey-National Metrology Institute (TUBITAK-UME) station, and a bulk deposition sampler was placed at the Kadilli village to determine the atmospheric deposition flux of polycyclic aromatic hydrocarbons (PAHs) and pesticides (organochlorine and organophosphorus) in soluble fraction of samples in Kocaeli, Turkey. The 28 samples for each wet, dry, and total deposition were collected weekly from March 2006 to March 2007. Gas chromatography-tandem mass spectrometry was used to analyze the samples which were prepared by using solid-phase extraction (SPE) method. The sum of volume weighted mean of deposition fluxes was obtained as 7.43 mu g m(-2) day(-1) for wet deposition, 0.28 mu g m(-2) day(-1) for dry deposition and 0.54 mu g m(-2) day(-1) for bulk deposition samples for PAHs and 9.88 mu g m(-2) day(-1) for wet deposition, 4.49 mu g m(-2) day(-1) for dry deposition, and 3.29 mu g m(-2) day(-1) for bulk deposition samples for pesticides. While benzo(a)anthracene had the highest fluxes among PAH compounds for all types of depositions, guthion and phosphamidon had the highest deposition flux compared with the other pesticides. Benzo(ghi)perylene, dibenz (a,h)anthracene, indeno(1,2,3-c,d)pyrene, benzo(a)pyrene, and acenaphthene were not detected in any of the samples. Beta-HCH, gamma-HCH, and endrin aldehyde were the only compounds among 18 organochlorine pesticides to be detected in all deposition samples. The main sources of pesticides were the high number of greenhouses around the sampling stations. However, all of the organophosphorus pesticides were detected in all deposition samples. The pollution sources were identified as coal and natural gas combustion, petrogenic sources, and traffic for TUBITAK-UME station whereas coal and natural gas combustion and traffic were the main sources for Kadilli station by considering the results of factor analysis, ratios, and wind sector analysis.en_US
dc.identifier.doi10.1007/s11356-013-2239-z
dc.identifier.endpage2917en_US
dc.identifier.issn0944-1344
dc.identifier.issn1614-7499
dc.identifier.issue4en_US
dc.identifier.pmid24154853en_US
dc.identifier.scopus2-s2.0-84893779747en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage2907en_US
dc.identifier.urihttps://doi.org/10.1007/s11356-013-2239-z
dc.identifier.urihttps://hdl.handle.net/20.500.12491/7981
dc.identifier.volume21en_US
dc.identifier.wosWOS:000331815100047en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.institutionauthorKarakaş, Serpil Yenisoy
dc.language.isoenen_US
dc.publisherSpringer Heidelbergen_US
dc.relation.ispartofEnvironmental Science And Pollution Researchen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectPAHen_US
dc.subjectPesticideen_US
dc.subjectFactor Analysisen_US
dc.subjectAtmospheric depositionen_US
dc.subjectIndustrial/Urban Area-Suburban Areaen_US
dc.titleSources of polycyclic hydrocarbons and pesticides in soluble fraction of deposition samples in Kocaeli, Turkeyen_US
dc.typeArticleen_US

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