Comparative elemental characterization of atmospheric fine and coarse PM samples by PIXE and ICP-MS/MS: results from a one-year measurement campaign in a coal-powered thermal power plant city

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dc.authorid0000-0001-7772-8858en_US
dc.authorid0000-0003-3870-8779en_US
dc.authorid0000-0003-3870-8779en_US
dc.authorid0000-0001-6508-6042en_US
dc.authorid0000-0002-8838-2060en_US
dc.contributor.authorDawood, Abdallah Munir Abdallah
dc.contributor.authorLucarelli, Franco
dc.contributor.authorAri, Akif
dc.contributor.authorCan, Emre
dc.contributor.authorArı, Pelin Ertürk
dc.contributor.authorDöğeroğlu, Tuncay
dc.date.accessioned2023-08-15T06:56:19Z
dc.date.available2023-08-15T06:56:19Z
dc.date.issued2022en_US
dc.departmentBAİBÜ, Mühendislik Fakültesi, Çevre Mühendisliği Bölümüen_US
dc.descriptionThis study was supported by the Scientific and Technological Research Council of Turkiye (TUBITAK) under the grant of 112Y305, and the Committee of Scientific Research Projects of Anadolu University under the grants of 1306F272, 1505F216, and 1508F606. The authors are also grateful to Dr Sinan Yatkin for his constructive comments. Special thanks to Prof. Franco Lucarelli's team members at the INFN laboratory for making their laboratory available and actively supporting the PIXE analysis of the samples.en_US
dc.description.abstractDaily fine (PM2.5) and coarse (PM2.5-10) particulate matter samples were collected from rural and urban monitoring stations located in an industrial region of mid-western Turkey, Kutahya city for one year. All fine- and coarse-mode samples were analyzed by both triple quadrupole inductively coupled plasma-mass spectrometry (ICP-MS/MS) and particle-induced X-ray emission (PIXE) techniques. The two techniques were comparatively evaluated and analytic performances were compared for 21 identified elements including Al, As, Br, Ca, Cr, Cu, Fe, Mg, Mn, Mo, Na, Ni, Pb, Rb, S, Se, Sr, Ti, V, Zn, and Zr. MDLs for PIXE were relatively higher than those of ICP-MS/MS by analyzing over 800 PM samples. The highest and lowest MDLs estimated for PIXE were in the range of 5.0 x 10(-3) (Na)-9 x 10(-6) mu g m(-3) (Ti) and between 8.5 x 10(-5) (S)-6 x 10(-8) mu g m(-3) (As) for ICP-MS/MS, respectively. Other metrics such as percent below the detection limit (% BDL), precision, and SRM recoveries were also used as variables of comparison. % BDL for PIXE varied between 0% (for Zn) and 83% (for Mo) with important marker elements such as Ca, S, K, Cl and Na being 4%, 8%, 11%, 12% and 21%, respectively. For ICP-MS/MS, % BDL varied between 0% (for Mg) and 98% (for Se) and important marker elements such as Na, Al, Ca, Cr, V and S were between 0% and 1% below detection. Absolute atmospheric concentration ratios (C-PIXE/CICP-MS/MS) of most elements except for Br, Mg, Na, and Zr were approximately 1, suggesting a good relationship between the two analytical techniques for elemental characterization of PM samples. In terms of atmospheric concentrations, the two techniques yielded almost the same magnitudes for the elements As, Br, Cr, Fe, Mn, Mo, Pb, Rb, Se, Sr, Ti, V, and Zn - hence, they were found to be equally competitive for measurement of these elements. Ca, Si, Ti, Cu, Zn, S, and Cl were detected in 90 to 100% of the samples. Likewise, Na, Mg, Al, S, Ca, Ti, V, Cr, Mn, Fe, Ni, and As were detected by ICP-MS/MS in almost every sample (similar to 99-100%).en_US
dc.description.sponsorshipScientific and Technological Research Council of Turkiye (TUBITAK); Committee of Scientific Research Projects of Anadolu University; [112Y305]; [1306F272]; [1505F216]; [1508F606]en_US
dc.identifier.citationDawood, A. M. A., Lucarelli, F., Arı, A., Can, E., Arı, P. E., Döğeroğlu, T., & Gaga, E. O. (2022). Comparative elemental characterization of atmospheric fine and coarse PM samples by PIXE and ICP-MS/MS: results from a one-year measurement campaign in a coal-powered thermal power plant city. Journal of Analytical Atomic Spectrometry, 37(12), 2701-2712.en_US
dc.identifier.doi10.1039/d2ja00251e
dc.identifier.endpage2712en_US
dc.identifier.issn0267-9477
dc.identifier.issn1364-5544
dc.identifier.issue12en_US
dc.identifier.scopus2-s2.0-85142426490en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage2701en_US
dc.identifier.urihttp://dx.doi.org/10.1039/d2ja00251e
dc.identifier.urihttps://hdl.handle.net/20.500.12491/11518
dc.identifier.volume37en_US
dc.identifier.wosWOS:000886379900001en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorArı, Akif
dc.institutionauthorArı, Pelin Ertürk
dc.language.isoenen_US
dc.publisherRoyal Society of Chemistryen_US
dc.relation.ispartofJournal of Analytical Atomic Spectrometryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.relation.tubitak[112Y305]
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectInductively-Coupled Plasmaen_US
dc.subjectParticulate Matteren_US
dc.subjectAir-Qualityen_US
dc.subjectChemical-Compositionen_US
dc.subjectTrace Analysisen_US
dc.subjectAerosolsen_US
dc.titleComparative elemental characterization of atmospheric fine and coarse PM samples by PIXE and ICP-MS/MS: results from a one-year measurement campaign in a coal-powered thermal power plant cityen_US
dc.typeArticleen_US

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