Simultaneous spectrometric determination of Cu(II), Co(II), and Ni(II) in pharmaceutical and environmental samples with XAD-4/DMMDTC solid-phase extraction system

Basit Öğe Kaydı
dc.authorid0000-0002-0374-3921
dc.contributor.authorTopuz, Berrin
dc.date.accessioned2021-06-23T19:55:00Z
dc.date.available2021-06-23T19:55:00Z
dc.date.issued2020
dc.departmentBAİBÜ, Mühendislik Fakültesi, Çevre Mühendisliği Bölümüen_US
dc.description.abstractA method for the preconcentration of Cu(II), Co(II), and Ni(II) based on their complex formation with the potassium salt of 2.6-dimethyl-morpholinedithiocarbamate (DMMDTC) and the Amberlite XAD-4 resin as a solid support in a column was suggested. Cu(II), Co(II), and Ni(II) were detected by using the suggested spectrophotometric method in Triton X-100 media. The analytes were adsorbed as DMMDTC complexes on Amberlite XAD-4 column at the pH range of 4-6 and eluted with 0.5 M HNO3 in acetone. The best possible enrichment factors for trace metal ions were achieved by optimizing the experimental conditions including reagent amount, eluent type, sample and eluent flow rates, sample volume, and the effects of matrix ions. The detection limits of Cu(II), Co(II), and Ni(II) were found to be 11.2, 26.1, and 1.37 mu g L-1, respectively. The accuracy of the proposed method was confirmed by determining the analytes in two Certified Reference Materials (TMDA-70.2 Ontario Lake Water and BCR-715 Waste Water) with the recoveries of more than 90%. The proposed method was successfully applied to the environmental and pharmaceutical samples.en_US
dc.identifier.doi10.1007/s12011-019-01930-0
dc.identifier.endpage302en_US
dc.identifier.issn0163-4984
dc.identifier.issn1559-0720
dc.identifier.issue1en_US
dc.identifier.pmid31641974en_US
dc.identifier.scopus2-s2.0-85074041097en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage295en_US
dc.identifier.urihttps://doi.org/10.1007/s12011-019-01930-0
dc.identifier.urihttps://hdl.handle.net/20.500.12491/10704
dc.identifier.volume194en_US
dc.identifier.wosWOS:000494199300001en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.institutionauthorTopuz, Berrin
dc.language.isoenen_US
dc.publisherHumana Press Incen_US
dc.relation.ispartofBiological Trace Element Researchen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectTrace Metalen_US
dc.subjectEnvironmental and Pharmaceutical Samplesen_US
dc.subjectSPE Methoden_US
dc.subjectSpectrophotometryen_US
dc.subject6-Dimethyl-morpholinedithiocarbamateen_US
dc.titleSimultaneous spectrometric determination of Cu(II), Co(II), and Ni(II) in pharmaceutical and environmental samples with XAD-4/DMMDTC solid-phase extraction systemen_US
dc.typeArticleen_US

Dosyalar

Orijinal paket
Listeleniyor 1 - 1 / 1
Küçük Resim Yok
İsim:
berrin-topuz.pdf
Boyut:
751.51 KB
Biçim:
Adobe Portable Document Format
Açıklama:
Tam Metin/Full Text
İndir

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
PubMed İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu
Çevre Mühendisliği Bölümü Koleksiyonu