In situ prepared tungsten(VI) oxide supported Pd0 NPs, remarkable activity and reusability in H2 releasing from dimethylamine borane

Basit Öğe Kaydı
dc.authorid0000-0003-2681-382Xen_US
dc.contributor.authorKaraboğa, Seda
dc.date.accessioned2023-05-12T06:35:18Z
dc.date.available2023-05-12T06:35:18Z
dc.date.issued2022en_US
dc.departmentBAİBÜ, Fen Edebiyat Fakültesi, Kimya Bölümüen_US
dc.description.abstractThe study reports preparation, characterization, and catalytic activity of Pd-0/WO3 nanoparticles in H-2 evolution from dimethylamine borane (DMAB). The active catalyst called Pd-0/WO3 NPs were obtained from the in situ reduction of Pd2+/WO3 precatalyst and tested in H-2 releasing from DMAB. Pd-0/WO3 NPs were found as remarkable catalysts providing a turnover frequency value of 948.0 h(-1) in H-2 releasing from DMAB at 60.0 +/- 0.5 degrees C. The results of some advanced analytical techniques reveal that Pd-0 NPs show uniform dispersion on the surface of tungsten(VI) oxide (WO3) with 5.85 +/- 0.57 nm of particle size. The reducible nature of tungsten(VI) oxide improves the catalytic efficiency of Pd-0/WO3 NPs in H-2 generation from DMAB. Pd-0/WO3 NPs were found as active catalysts even after the 6th run of dehydrogenation reaction. The report also covers the kinetic performance of the catalyst.en_US
dc.identifier.citationKARABOĞA, S. (2022). In situ prepared tungsten (VI) oxide supported Pd0 NPs, remarkable activity andreusability in H2 releasing from dimethylamine borane. Turkish Journal of Chemistry, 46(2), 394-403.en_US
dc.identifier.doi10.3906/kim-2110-45
dc.identifier.endpage403en_US
dc.identifier.issn1300-0527
dc.identifier.issue2en_US
dc.identifier.scopus2-s2.0-85129310658en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage394en_US
dc.identifier.trdizinid530278en_US
dc.identifier.urihttp://dx.doi.org/10.3906/kim-2110-45
dc.identifier.urihttps://hdl.handle.net/20.500.12491/10868
dc.identifier.volume46en_US
dc.identifier.wosWOS:000771067100001en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakTR-Dizinen_US
dc.institutionauthorKaraboğa, Seda
dc.language.isoenen_US
dc.publisherScientific Technical Research Council Turkey - TUBİTAKen_US
dc.relation.ispartofTurkish Journal Of Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectPd-0 Nanoparticlesen_US
dc.subjectTungsten(VI) Oxideen_US
dc.subjectDehydrogenationen_US
dc.subjectMetal-Organic Frameworken_US
dc.subjectBoron-Nitrogen Bondsen_US
dc.subjectCopper(0) Nanoparticlesen_US
dc.titleIn situ prepared tungsten(VI) oxide supported Pd0 NPs, remarkable activity and reusability in H2 releasing from dimethylamine boraneen_US
dc.typeArticleen_US

Dosyalar

Orijinal paket
Listeleniyor 1 - 1 / 1
Küçük Resim
İsim:
seda-karaboga.pdf
Boyut:
1.84 MB
Biçim:
Adobe Portable Document Format
Açıklama:
Tam Metin/Full Text
İndir
Lisans paketi
Listeleniyor 1 - 1 / 1
Küçük Resim Yok
İsim:
license.txt
Boyut:
1.44 KB
Biçim:
Item-specific license agreed upon to submission
Açıklama:
İndir

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Kimya Bölümü Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu
TR-Dizin İndeksli Yayınlar Koleksiyonu