In situ prepared tungsten(VI) oxide supported Pd0 NPs, remarkable activity and reusability in H2 releasing from dimethylamine borane
Yükleniyor...
Dosyalar
Tarih
2022
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Scientific Technical Research Council Turkey - TUBİTAK
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
The study reports preparation, characterization, and catalytic activity of Pd-0/WO3 nanoparticles in H-2 evolution from dimethylamine borane (DMAB). The active catalyst called Pd-0/WO3 NPs were obtained from the in situ reduction of Pd2+/WO3 precatalyst and tested in H-2 releasing from DMAB. Pd-0/WO3 NPs were found as remarkable catalysts providing a turnover frequency value of 948.0 h(-1) in H-2 releasing from DMAB at 60.0 +/- 0.5 degrees C. The results of some advanced analytical techniques reveal that Pd-0 NPs show uniform dispersion on the surface of tungsten(VI) oxide (WO3) with 5.85 +/- 0.57 nm of particle size. The reducible nature of tungsten(VI) oxide improves the catalytic efficiency of Pd-0/WO3 NPs in H-2 generation from DMAB. Pd-0/WO3 NPs were found as active catalysts even after the 6th run of dehydrogenation reaction. The report also covers the kinetic performance of the catalyst.
Açıklama
Anahtar Kelimeler
Pd-0 Nanoparticles, Tungsten(VI) Oxide, Dehydrogenation, Metal-Organic Framework, Boron-Nitrogen Bonds, Copper(0) Nanoparticles
Kaynak
Turkish Journal Of Chemistry
WoS Q Değeri
Q4
Scopus Q Değeri
Q3
Cilt
46
Sayı
2
Künye
KARABOĞA, S. (2022). In situ prepared tungsten (VI) oxide supported Pd0 NPs, remarkable activity andreusability in H2 releasing from dimethylamine borane. Turkish Journal of Chemistry, 46(2), 394-403.
