H2(g) production from dimethylamine borane by Cu0/WO3 NPs catalyst

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dc.authorid0000-0003-2681-382Xen_US
dc.authorid0000-0002-7585-0136en_US
dc.contributor.authorAl-Hameedaw, Doaa
dc.contributor.authorKaraboğa, Seda
dc.contributor.authorMorkan, İzzet
dc.date.accessioned2024-03-13T11:16:13Z
dc.date.available2024-03-13T11:16:13Z
dc.date.issued2023en_US
dc.departmentBAİBÜ, Fen Edebiyat Fakültesi, Kimya Bölümüen_US
dc.description.abstractCu0 NPs supported on tungsten (VI) oxide (WO3) were in situ generated from the reduction of Cu2+ ions during dehydrogenation of dimethylamine borane (DMAB). The Cu0/WO3 NPs displayed tangible catalytic activity in H2 (g) releasing reaction and they were identified by using advanced techniques. Cu0/WO3 NPs were found as active catalyst providing one equiv. H2(g) per mole of DMAB. The results from TEM images display the formation of Cu0 NPs with an average particle size of 4.6 ± 1.0 nm on the surface of WO3. Moreover, Cu0/WO3 NPs with various metal loadings were prepared and tested as catalyst in dehydrogenation reaction to find the optimum metal loading on WO3 support. The highest H2 generation rate was achieved for 4.0% wt. Cu0/WO3 catalyst with TOF value of 39 h?1 in the reaction conditions. Additionally, effect of various catalyst concentration and temperature is discussed on the reaction kinetics for reaction catalyzed by Cu0/WO3 NPs.en_US
dc.identifier.citationAl-Hameedawi, D., Karaboğa, S., & Morkan, I. (2023). H2 (g) production from dimethylamine borane by Cu0/WO3 NPs catalyst. Turkish Journal of Chemistry, 47(2), 436-447.en_US
dc.identifier.doi10.55730/1300-0527.3550
dc.identifier.endpage447en_US
dc.identifier.issn1300-0527
dc.identifier.issue2en_US
dc.identifier.pmid37528933en_US
dc.identifier.scopus2-s2.0-85162114797en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage436en_US
dc.identifier.trdizinid1180471en_US
dc.identifier.urihttp://dx.doi.org/10.55730/1300-0527.3550
dc.identifier.urihttps://hdl.handle.net/20.500.12491/12080
dc.identifier.volume47en_US
dc.identifier.wosWOS:000996094100012en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakTR-Dizinen_US
dc.indekslendigikaynakPubMeden_US
dc.institutionauthorKaraboğa, Seda
dc.institutionauthorMorkan, İzzet
dc.language.isoenen_US
dc.publisherScientific and Technological Research Council Turkeyen_US
dc.relation.ispartofTurkish Journal of Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectH2 (G) Generationen_US
dc.subjectDimethylamine Boraneen_US
dc.subjectCu0 Nanoparticlesen_US
dc.subjectTungsten(VI) Oxideen_US
dc.subjectHeterogeneous Catalysisen_US
dc.subjectNanoparticles Catalysten_US
dc.titleH2(g) production from dimethylamine borane by Cu0/WO3 NPs catalysten_US
dc.typeArticleen_US

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