Crystal structure and thermal analysis of new mononuclear nickel (II) complexes with NNN type pyrazolyl ligands and halids

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dc.authorid0000-0002-2991-9702en_US
dc.authorid0000-0001-6974-513Xen_US
dc.authorid0000-0002-6311-8917
dc.authorid0000-0003-0977-6588
dc.contributor.authorTaştekin, Mustafa
dc.contributor.authorDurmuş, Sefa
dc.contributor.authorŞahin, Ertan
dc.contributor.authorArıcı, Cengiz
dc.contributor.authorEmregül, Kaan Cebesoy
dc.contributor.authorAtakol, Orhan
dc.date.accessioned2021-06-23T19:26:01Z
dc.date.available2021-06-23T19:26:01Z
dc.date.issued2008
dc.departmentBAİBÜ, Eğitim Fakültesi, Matematik ve Fen Bilimleri Eğitimien_US
dc.description.abstractMononuclear Ni(II) complexes of Bis-2,6(pyrazolyl)pyridine(pp), 2(1-pyrazolyl)-6-(3,5-dimethylpyrazol-1-yl)pyridine(mpp) and bis-2,6(3,5-dimethyl-pyrazolyl-lyl)pyridine(dmpp) were prepared in MeOH:H(2)O mixtures. The complexes were characterized using elemental analysis, IR spectroscopy, X-ray diffraction and thermal analysis. The molecular structure of [Nidmpp(H(2)O)(2)Br]Br was evaluated and the Ni(II) ion was found to be in a distorted octahedral coordination environment. One of. the halogen ions was found to coordinate the Ni(H) ion whereas the other ion does not coordinate and forms hydrogen bonds with the water molecules situated on the neighboring complex molecules, resulting in a supramolecular arrangement. Thermogravimetric results showed three coordinated water molecules in the pp and mpp complexes. Conductometric and potentiometric studies of the complexes showed 2 and 1 turning points, respectively.en_US
dc.identifier.doi10.1524/zkri.2008.0043
dc.identifier.endpage429en_US
dc.identifier.issn0044-2968
dc.identifier.issue6en_US
dc.identifier.scopus2-s2.0-47349095539en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage424en_US
dc.identifier.urihttps://doi.org/10.1524/zkri.2008.0043
dc.identifier.urihttps://hdl.handle.net/20.500.12491/6377
dc.identifier.volume223en_US
dc.identifier.wosWOS:000258460700007en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorDurmuş, Sefa
dc.language.isoenen_US
dc.publisherOldenbourg Verlagen_US
dc.relation.ispartofZeitschrift Fur Kristallographieen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectThermal Analysisen_US
dc.subjectNi Complexesen_US
dc.subjectNNN Type Liganden_US
dc.subjectCrystal Structure Analysisen_US
dc.subjectX-ray Diffractionen_US
dc.titleCrystal structure and thermal analysis of new mononuclear nickel (II) complexes with NNN type pyrazolyl ligands and halidsen_US
dc.typeArticleen_US

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