Potentiometric and spectroscopic determinaton of acid dissociation constants of some phenols and salicylic acids
Küçük Resim Yok
Tarih
1997
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
The dissociation constant of the catechol derivatives 4-nitrocatechol (NCAT), 2,3-dihydroxybenzoic acid (2,3-DHBA), 3,4-dihydroxybenzoic acid (3,4-DBHA), 3,4-dihydroxyhenylacetic acid (3,4-DPHA) and 3,4-dihydroxycinnamic acid (3,4-DHCA) were identified in 0.1M NaClO4 ionic medium, at t=25° C, by potentiometry. In addition, the first and second dissociation constants of the salicylic acid derivatives 5-nitrosalicylic acid (5-NSA), 4-hydroxysalicylic acid (4-HSA) 5-nitrosalicylic acid (5-HSA) were also determined by potentiometry. Furthermore, the second acid dissociation constants of these ligands were evaluated in I=0.1M NaClO4 ionic medium, at a temperature of 25° C by computer analysis of spectroscopic data.
Açıklama
Anahtar Kelimeler
Acid Dissociation Constants, Catechol Derivatives, Salicylic acid derivatives
Kaynak
Turkish Journal of Chemistry
WoS Q Değeri
Scopus Q Değeri
Q3
Cilt
21
Sayı
4
