Magnetic properties of trinuclear Ni-M-Ni complexes, M = Mn, Co and Ni
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Dosyalar
Tarih
2006
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Elsevier
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
A tetradentate ligand, abbr. L2- =dmSALPD(2-) = N,N'-bis(sahcylidene)-1,3-propanediaminato dianion, has been complexed with metal ions in the presence of dimethylformamide (dmf) and nitrite anion. As a result, trinuclear molecular complexes of the type [M-II- {Ni(NO2(L2-)(dmf)}(2)], where M-II = Mn(II), Co(II) and Ni(II) were obtained. The magnetic susceptibility and magnetization data were treated simultaneously during the fitting procedure. In addition to the isotropic exchange, the zero-field splitting parameters D-A were added to the spin Hamiltonian. An anti-ferromagnetic interaction was found in all complexes and the single ion magnetic anisotropy parameter for the Ni(II) peripheral centers adopt considerable values.
Açıklama
Anahtar Kelimeler
Magnetic Properties, Trinuclear, Nickel Compounds, Ferromagnetism
Kaynak
Chemical Physics Letters
WoS Q Değeri
Q2
Scopus Q Değeri
Cilt
423
Sayı
1-3
