Quantifying spatial variability of peat soil carbon and nitrogen using infrared spectroscopy, statistical and geo-statistical models

Küçük Resim Yok

Tarih

2011

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

Dr Jyoti Garg

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

Chemical and biological analyses of soil carbon (C) and nitrogen (N) are time-consuming or require fresh material in cases of intensive in situ sampling. Infrared spectroscopy is one of the rapid and non-destructive methods that can be applied to a large number of soil samples. In this study, Attenuated Total Reflectance (ATR) Fourier transform infrared (FTIR) spectroscopy in the range of 600 to 4000 cm(-1) was assessed using partial least squares (PLS) regression model to predict total C and N of peat soils. ATR/FTIR-based PLS models had r(2) values of about 0.8 for fitted functions and 0.7 for leave-one-out cross-validations. Using an independent dataset to compare soil C and N values estimated by ATR/FTIR-based PLS models versus those measured using CHN elemental analyzer led to r(2) value of 0.97 for both soil C and N. The combined use of ATR/FTIR-based PLS models and inverse distance weighting (IDW) interpolation appears to be a promising method to estimate total C and N of peat soils for rapid data acquisition across spatially extensive areas.

Açıklama

Anahtar Kelimeler

Biogeochemical Cycles, Environmental Monitoring, Peatland, Soil Quality, PLS, IR, ATR-FTIR

Kaynak

Research Journal Of Chemistry And Environment

WoS Q Değeri

Q4

Scopus Q Değeri

Q4

Cilt

15

Sayı

4

Künye