Rhodium(0) nanoparticles supported on nanotitania as highly active catalyst in hydrogen generation from the hydrolysis of ammonia borane

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dc.authorid0000-0003-3858-2985en_US
dc.authorid0000-0002-6302-1429en_US
dc.authorid0000-0003-1790-6143
dc.authorid0000-0002-2004-2676
dc.contributor.authorAkbayrak, Serdar
dc.contributor.authorGençtürk, Serap
dc.contributor.authorMorkan, İzzet
dc.contributor.authorÖzkar, Saim
dc.date.accessioned2021-06-23T19:37:08Z
dc.date.available2021-06-23T19:37:08Z
dc.date.issued2014
dc.departmentBAİBÜ, Fen Edebiyat Fakültesi, Kimya Bölümüen_US
dc.description.abstractRhodium(0) nanoparticles supported on the surface of titanium dioxide (Rh(0)@TiO2) were in situ generated from the reduction of rhodium(III) ions impregnated on nanotitania during the hydrolysis of ammonia borane. They were isolated from the reaction solution by centrifugation and characterized by a combination of advanced analytical techniques. The results show that (i) highly dispersed rhodium(0) nanoparticles with sizes in the range 1.3-3.8 nm were formed on the surface of titanium dioxide, (ii) Rh(0)@TiO2 shows high catalytic activity in hydrogen generation from the hydrolysis of ammonia borane with a turnover frequency value up to 260 min(-1) at 25.0 +/- 0.1 degrees C, (iii) the results of kinetic studies on the hydrogen generation from the hydrolysis of ammonia borane were also reported including the activation energy of 65.5 +/- 2 kJ mol(-1) for this reaction.en_US
dc.identifier.doi10.1039/c4ra00469h
dc.identifier.endpage13748en_US
dc.identifier.issn2046-2069
dc.identifier.issue26en_US
dc.identifier.scopus2-s2.0-84896345340en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage13742en_US
dc.identifier.urihttps://doi.org/10.1039/c4ra00469h
dc.identifier.urihttps://hdl.handle.net/20.500.12491/8112
dc.identifier.volume4en_US
dc.identifier.wosWOS:000333082700070en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorGençtürk, Serap
dc.institutionauthorMorkan, İzzet
dc.language.isoenen_US
dc.publisherRoyal Soc Chemistryen_US
dc.relation.ispartofRsc Advancesen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.titleRhodium(0) nanoparticles supported on nanotitania as highly active catalyst in hydrogen generation from the hydrolysis of ammonia boraneen_US
dc.typeArticleen_US

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