The first enzymatic resolution of quaternary alpha '-acetoxy alpha,beta-unsaturated cyclohexenones and cyclopentenones

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dc.authorid0000-0003-2270-8635en_US
dc.authorid0000-0002-9553-6419en_US
dc.contributor.authorTanyeli, Cihangir
dc.contributor.authorÖzdemirhan, Fazilet Devrim
dc.contributor.authorİyigün, Çiğdem
dc.date.accessioned2021-06-23T19:18:07Z
dc.date.available2021-06-23T19:18:07Z
dc.date.issued2005
dc.departmentBAİBÜ, Fen Edebiyat Fakültesi, Kimya Bölümüen_US
dc.description.abstractThe enantio selective resolution of various quaternary alpha'-acetoxy alpha,beta-unsaturated cyclohexenones and cyclopentenones was performed with the commercially available enzyme CCL in pH = 8.0 phosphate buffer. Various parameters that would affect the enantioselectivities were tested and the best enzymatic resolution conditions were found to afford the enantiomerically enriched quaternary acetoxylated substrates with high ee varying between 36% and 99%.en_US
dc.identifier.doi10.1016/j.tetasy.2005.11.016
dc.identifier.endpage4055en_US
dc.identifier.issn0957-4166
dc.identifier.issue24en_US
dc.identifier.scopus2-s2.0-28844483771en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage4050en_US
dc.identifier.urihttps://doi.org/10.1016/j.tetasy.2005.11.016
dc.identifier.urihttps://hdl.handle.net/20.500.12491/5645
dc.identifier.volume16en_US
dc.identifier.wosWOS:000234195500017en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorÖzdemirhan, Fazilet Devrim
dc.language.isoenen_US
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.ispartofTetrahedron-Asymmetryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCyclopentenonesen_US
dc.subjectEnzymatic
dc.subjectCyclohexenones
dc.subjectQuaternary
dc.titleThe first enzymatic resolution of quaternary alpha '-acetoxy alpha,beta-unsaturated cyclohexenones and cyclopentenonesen_US
dc.typeArticleen_US

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