Two new mononuclear Ni(II) complexes with reduced ONNO type schiff base
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Dosyalar
Tarih
2005
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Walter De Gruyter Gmbh
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
N,N'-bis(salicylidene)-1,3-propanediamine (LH2) and N,N'-bis(salicylidene)-2,2'-dimethyl-1,3-propanediamine (DMLH2) were reduced to phenolic amines by using NaBH4. Mononuclear complexes were obtained with Ni (II) in a N3O6 coordination sphere with these amines and N3- ions, in DMF media. It was established with the XRD studies that the coordination spheres were distorted octahedral and the complex obtained with LH2 formed dimeric structures via phenolic OH bonds. The other complex was seen to have monomeric structure. The complexes were characterized by X-ray diffraction, elemental analysis, termogravimetry, IR spectroscopy and simple magnetic susceptibility (Gouy method). In addition, cyclic voltammetric studies have been performed.
Açıklama
Anahtar Kelimeler
Mononuclear Ni Complexes, Cyclic Voltammetry, Single Crystal Structure Analysis, X-ray Diffraction
Kaynak
Zeitschrift Fur Kristallographie
WoS Q Değeri
Q2
Scopus Q Değeri
N/A
Cilt
220
Sayı
11
