Zinc-mediated efficient and environmentally benign synthesis of salicylate esters

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dc.authorid0000-0002-0035-9262
dc.authorid0000-0003-0759-334X
dc.contributor.authorTaşdemir, Harun
dc.contributor.authorTraş, Semih
dc.contributor.authorÇat, Yeşim
dc.contributor.authorGürer, Sonay
dc.contributor.authorSağırlı, Akın
dc.date.accessioned2024-09-25T19:59:57Z
dc.date.available2024-09-25T19:59:57Z
dc.date.issued2024
dc.departmentBAİBÜ, Fen Edebiyat Fakültesi, Kimya Bölümü en_US
dc.description.abstractConsiderable synthetic effort has been devoted to acid- or base-catalysed transesterification of alkyl salicylate with alcohol in order to synthesize salicylate esters efficiently. In this study, the transesterification of methyl salicylate with 12 different alcohols was carried out by the use of Zn dust as a catalyst. Depending on the alcohol used in the transesterification reaction, the completion of the reaction was within a range of 8-15 h at a temperature between 100 and 170 degrees C. The use of Zn dust provided reusability and almost complete recovery with moderate to excellent yields (42%-97%). The structural elucidation of the products was performed using IR, 1H NMR, 13C NMR and GC-MS data obtained from the Wiley GC/MS Library and the in-house Parkim Fragrance House GC/MS Library. Zn-Mediated Synthesis of Some Commercially Available Salicylate Esters in Solvent-Free Conditions.imageen_US
dc.description.sponsorshipThe authors are grateful to Associate Professor Dr. Erhan Budak for infrared measurements.en_US
dc.identifier.doi10.1002/ffj.3800
dc.identifier.endpage301en_US
dc.identifier.issn0882-5734
dc.identifier.issn1099-1026
dc.identifier.issue5en_US
dc.identifier.scopus2-s2.0-85197421905en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage293en_US
dc.identifier.urihttps://doi.org/10.1002/ffj.3800
dc.identifier.urihttps://hdl.handle.net/20.500.12491/13998
dc.identifier.volume39en_US
dc.identifier.wosWOS:001257203300001en_US
dc.identifier.wosqualityN/Aen_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorSağırlı, Akın
dc.institutionauthorid0000-0003-0759-334X
dc.language.isoenen_US
dc.publisherWileyen_US
dc.relation.ispartofFlavour and Fragrance Journalen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.snmzYK_20240925en_US
dc.subjectSalicylate Estersen_US
dc.subjectTrans-Esterificationen_US
dc.subjectZn dusten_US
dc.subjectAlcohols
dc.subjectTransesterification Reaction
dc.titleZinc-mediated efficient and environmentally benign synthesis of salicylate estersen_US
dc.typeArticleen_US

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