Investigation on the thermal decomposition some heterodinuclear Ni-II-M-II complexes prepared from onno type reduced Schiff base compounds (M-II=Zn-II, Cd-II)

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dc.authorid0000-0002-2991-9702en_US
dc.authorid0000-0001-6974-513Xen_US
dc.authorid0000-0002-9405-1217en_US
dc.authorid0000-0003-1304-7126
dc.contributor.authorAksu, Mecit
dc.contributor.authorDurmuş, Sefa
dc.contributor.authorSarı, Musa
dc.contributor.authorEmregül, Kaan
dc.contributor.authorSvoboda, I.
dc.date.accessioned2021-06-23T19:19:46Z
dc.date.available2021-06-23T19:19:46Z
dc.date.issued2007
dc.departmentBAİBÜ, Eğitim Fakültesi, Matematik ve Fen Bilimleri Eğitimien_US
dc.description32nd Workshop on Heterogeneous Equilibria between Phases (JEEP 2006) -- MAR 30-31, 2006 -- Univ Rouen, Rouen, FRANCEen_US
dc.description.abstractN,N'-bis(salicylidene)-1,3-propanediamine (LH2), N,N'-bis(salicylidene)-2,2'-dimethyl-1,3-propanediamine (LDMH2), N,N'-bis(salicylidene)-2-hydroxy-1,3-propanediamine (LOH3), N,N'-bis(2-hydroxyacetophenylidene)-1,3-propanediamine (LACH(2)) and N,N'-bis(2-hydroxyacetophenone)-2,2'-dimethyl-1,3-propanediamine (LACDMH(2)) were synthesized and reduced to their phenol-amine form in alcoholic media using NaBH4 ((LH2)-H-H, (LDMH2)-H-H, (LOH2)-H-H, LAC(H)H(2) and LACDM(H)H(2)). Heterodinuclear complexes were synthesized using Ni(II), Zn(II) and Cd(II) salts, according to the template method in DMF media. The complex structures were analyzed using elemental analysis, IR spectroscopy, and thermogravimetry. Suitable crystals of only one complex were obtained and its structure determined using X-ray diffraction, NiLAC(H)center dot CdBr2 center dot DMF2, space group orthorhombic, Pbca, a=20.249, b=14.881, c=20.565 angstrom and Z=8. The heterodinuclear complexes were seen to be of [Ni center dot ligand center dot MX2 center dot DMF2] structure (ligand=LH2-, LDMH2-, LOHH2-, LAC(H2-), LACDM(H2-), M=Zn-II, Cd-II, X=Br-, I-). Thermogravimetric analysis showed irreversible bond breakage of the coordinatively bonded DMF molecules followed by decomposition at this temperature.en_US
dc.identifier.doi10.1007/s10973-006-7729-5
dc.identifier.endpage547en_US
dc.identifier.issn1388-6150
dc.identifier.issue2en_US
dc.identifier.scopus2-s2.0-36849032798en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage541en_US
dc.identifier.urihttps://doi.org/10.1007/s10973-006-7729-5
dc.identifier.urihttps://hdl.handle.net/20.500.12491/6000
dc.identifier.volume90en_US
dc.identifier.wosWOS:000251088600036en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorDurmuş, Sefa
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofJournal Of Thermal Analysis And Calorimetryen_US
dc.relation.publicationcategoryKonferans Öğesi - Uluslararası - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCrystal Structureen_US
dc.subjectHeterodinuclear Complexesen_US
dc.subjectONNO type Schiff Basesen_US
dc.subjectThermal Analysisen_US
dc.titleInvestigation on the thermal decomposition some heterodinuclear Ni-II-M-II complexes prepared from onno type reduced Schiff base compounds (M-II=Zn-II, Cd-II)en_US
dc.typeConference Objecten_US

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