Mn(III)-based C-C bond formation: regioselective alpha '-allylation of various alpha, beta-unsaturated, alpha and beta-alkoxy alpha,beta-unsaturated ketones

dc.authorid0000-0003-2270-8635en_US
dc.contributor.authorTanyeli, Cihangir
dc.contributor.authorÖzdemirhan, Devrim
dc.date.accessioned2021-06-23T19:18:17Z
dc.date.available2021-06-23T19:18:17Z
dc.date.issued2005
dc.departmentBAİBÜ, Fen Edebiyat Fakültesi, Kimya Bölümüen_US
dc.description.abstractThe Manganese(III) -based regioselective alpha'-keto radical generation of unsaturated ketones is a versatile synthetic procedure with broad applicability. The generated alpha'-keto radical slowly creates a metal enolate in a solvent at reflux. The resultant metal enolate affords the corresponding alpha'-allylated alpha,beta-unsaturated ketones in good yields. This method is the first example of the metal mediated regioselective alpha'-allylation of alpha,beta-unsaturated ketones. The ketones that have alpha or beta-alkoxy groups also work efficiently.en_US
dc.identifier.doi10.1016/j.tet.2005.06.031
dc.identifier.endpage8217en_US
dc.identifier.issn0040-4020
dc.identifier.issue34en_US
dc.identifier.scopus2-s2.0-22544443924en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage8212en_US
dc.identifier.urihttps://doi.org/10.1016/j.tet.2005.06.031
dc.identifier.urihttps://hdl.handle.net/20.500.12491/5688
dc.identifier.volume61en_US
dc.identifier.wosWOS:000230982500015en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorÖzdemirhan, Devrim
dc.language.isoenen_US
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.ispartofTetrahedronen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectEnonesen_US
dc.subjectManganese and Compoundsen_US
dc.subjectAllylationen_US
dc.titleMn(III)-based C-C bond formation: regioselective alpha '-allylation of various alpha, beta-unsaturated, alpha and beta-alkoxy alpha,beta-unsaturated ketonesen_US
dc.typeArticleen_US

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