Mn(III)-based C-C bond formation: regioselective alpha '-allylation of various alpha, beta-unsaturated, alpha and beta-alkoxy alpha,beta-unsaturated ketones
dc.authorid | 0000-0003-2270-8635 | en_US |
dc.contributor.author | Tanyeli, Cihangir | |
dc.contributor.author | Özdemirhan, Devrim | |
dc.date.accessioned | 2021-06-23T19:18:17Z | |
dc.date.available | 2021-06-23T19:18:17Z | |
dc.date.issued | 2005 | |
dc.department | BAİBÜ, Fen Edebiyat Fakültesi, Kimya Bölümü | en_US |
dc.description.abstract | The Manganese(III) -based regioselective alpha'-keto radical generation of unsaturated ketones is a versatile synthetic procedure with broad applicability. The generated alpha'-keto radical slowly creates a metal enolate in a solvent at reflux. The resultant metal enolate affords the corresponding alpha'-allylated alpha,beta-unsaturated ketones in good yields. This method is the first example of the metal mediated regioselective alpha'-allylation of alpha,beta-unsaturated ketones. The ketones that have alpha or beta-alkoxy groups also work efficiently. | en_US |
dc.identifier.doi | 10.1016/j.tet.2005.06.031 | |
dc.identifier.endpage | 8217 | en_US |
dc.identifier.issn | 0040-4020 | |
dc.identifier.issue | 34 | en_US |
dc.identifier.scopus | 2-s2.0-22544443924 | en_US |
dc.identifier.scopusquality | Q2 | en_US |
dc.identifier.startpage | 8212 | en_US |
dc.identifier.uri | https://doi.org/10.1016/j.tet.2005.06.031 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12491/5688 | |
dc.identifier.volume | 61 | en_US |
dc.identifier.wos | WOS:000230982500015 | en_US |
dc.identifier.wosquality | Q2 | en_US |
dc.indekslendigikaynak | Web of Science | en_US |
dc.indekslendigikaynak | Scopus | en_US |
dc.institutionauthor | Özdemirhan, Devrim | |
dc.language.iso | en | en_US |
dc.publisher | Pergamon-Elsevier Science Ltd | en_US |
dc.relation.ispartof | Tetrahedron | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Enones | en_US |
dc.subject | Manganese and Compounds | en_US |
dc.subject | Allylation | en_US |
dc.title | Mn(III)-based C-C bond formation: regioselective alpha '-allylation of various alpha, beta-unsaturated, alpha and beta-alkoxy alpha,beta-unsaturated ketones | en_US |
dc.type | Article | en_US |
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