The effect of cobalt and boron on the structural, microstructural, and optoelectronic properties of ZnO nanoparticles

Basit Öğe Kaydı
dc.authorid0000-0002-1301-6963en_US
dc.authorid0000-0003-0722-3891en_US
dc.authorid0000-0002-5322-963X
dc.contributor.authorŞenol, Sevim Demirözü
dc.contributor.authorÖzuğurlu, Ersin
dc.contributor.authorArda, Lütfi
dc.date.accessioned2021-06-23T19:54:20Z
dc.date.available2021-06-23T19:54:20Z
dc.date.issued2020
dc.departmentBAİBÜ, Fen Edebiyat Fakültesi, Kimya Bölümüen_US
dc.description.abstractCo/B co-doped ZnO (Zn0.93-xCoxB0.07O , x = 0.00, 0.01, 0.02, 0.03, 0.04, and 0.05) nanoparticles were synthesized by the hydrothermal method to investigate the effect of cobalt and boron on the structural, microstructural, and optoelectronic properties of ZnO nanoparticles. The X-ray diffraction method was used for the structural analysis and single phases were found for all Co/B co-doped ZnO nanoparticles. Scanning Electron Microscope (SEM) technique was used to determine the surface morphology, particle size, and the shapes of the nanoparticles. LThe elemental compositions of the nanoparticles were obtained by electron dispersive spectroscopy (EDS). Hexagonal Wurtzite structure was proved by c/a ratios of the ZnCoBO nanoparticles. The Fourier transform infrared (FTIR) studies were performed and explained. The energy band gaps of the samples were calculated and the effects of dopant elements on optical properties were discussed. The maximum band gap occurred for Zn0.93B0.70 with a band gap energy of E-g = 3.26 eV. The refractive index was calculated using the energy band gap with five different models. The grain sizes and the band gap energies fluctuated as the doping ratio increased. The results showed that the refractive index strongly depends on the Co concentration nonlinearly. It was found that doping cobalt increased the Urbach energy value of B-doped ZnO nanoparticles. The increase in E u indicates that the structural disorder and the number of defects in the Zn0.93-xCoxB0.07O structures increased with increasing concentration of Co in the Zn0.93-xCoxB0.07O structures. The highest value of Urbach energy was approximately found in the range of 1259 and 1469 meV for 3% Co. Moreover, for 3% Co the concentration-dependent microstrain (epsilon) values also reached the maximum, dislocation density 8 had also the maximum value.en_US
dc.identifier.doi10.1016/j.ceramint.2019.11.193
dc.identifier.endpage7044en_US
dc.identifier.issn0272-8842
dc.identifier.issn1873-3956
dc.identifier.issue6en_US
dc.identifier.scopus2-s2.0-85075883999en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage7033en_US
dc.identifier.urihttps://doi.org/10.1016/j.ceramint.2019.11.193
dc.identifier.urihttps://hdl.handle.net/20.500.12491/10506
dc.identifier.volume46en_US
dc.identifier.wosWOS:000519661800006en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorŞenol, Sevim Demirözü
dc.language.isoenen_US
dc.publisherElsevier Sci Ltden_US
dc.relation.ispartofCeramics Internationalen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectZinc Oxideen_US
dc.subjectNanoparticlesen_US
dc.subjectEnergy Gapen_US
dc.subjectRefractive Indexen_US
dc.subjectUrbach Energyen_US
dc.titleThe effect of cobalt and boron on the structural, microstructural, and optoelectronic properties of ZnO nanoparticlesen_US
dc.typeArticleen_US

Dosyalar

Orijinal paket
Listeleniyor 1 - 1 / 1
Küçük Resim Yok
İsim:
sevim-demirozu-senol.pdf
Boyut:
4.07 MB
Biçim:
Adobe Portable Document Format
Açıklama:
Tam Metin/Full Text
İndir

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Kimya Bölümü Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu