Intermediate products in solid-state reactions of gadolinium oxide and ammonium dihydrogen phosphate

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dc.authorid0000-0002-5322-963Xen_US
dc.authorid0000-0002-7585-0136
dc.authorid0000-0001-7546-5230
dc.authorid0000-0003-1790-6143
dc.contributor.authorMorkan, Ayşe Üztetik
dc.contributor.authorMorkan, İzzet
dc.contributor.authorDemirözü, Sevim Şenol
dc.contributor.authorGüler, Hikmet
dc.date.accessioned2021-06-23T19:19:49Z
dc.date.available2021-06-23T19:19:49Z
dc.date.issued2007
dc.departmentBAİBÜ, Fen Edebiyat Fakültesi, Kimya Bölümüen_US
dc.description.abstractThe solid-state reactions of Gd2O3 with NH4H2PO4 using various molar ratios (3:6, 2:8, 1:6 and 1:8) of the reactants were investigated at different temperatures (350-1100 degrees C) to observe the intermediate compounds. Analysis of the X-ray powder diffraction patterns of the products obtained at 350 degrees C; for the compositions of 2:8, 1:6 and 1:8 molar ratios revealed the formation of a new compound, NH4GdHP3O10 which was reported previously for Nd, Ho and Er. At higher temperatures, gadolinium tripolyphosphate was obtained for all of the molar ratios. On the other hand, the IR data of the products also confirmed the proposed reaction pathways. (c) 2007 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.en_US
dc.identifier.doi10.1002/crat.200710971
dc.identifier.endpage1013en_US
dc.identifier.issn0232-1300
dc.identifier.issue10en_US
dc.identifier.scopus2-s2.0-35248867020en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage1007en_US
dc.identifier.urihttps://doi.org/10.1002/crat.200710971
dc.identifier.urihttps://hdl.handle.net/20.500.12491/6008
dc.identifier.volume42en_US
dc.identifier.wosWOS:000250113400012en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorMorkan, Ayşe Üztetik
dc.institutionauthorMorkan, İzzet
dc.institutionauthorDemirözü, Sevim Şenol
dc.language.isoenen_US
dc.publisherWiley-V C H Verlag Gmbhen_US
dc.relation.ispartofCrystal Research And Technologyen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectGadoliniumen_US
dc.subjectPhosphatesen_US
dc.subjectSolid Stateen_US
dc.subjectXRDen_US
dc.subjectIR Spectroscopyen_US
dc.titleIntermediate products in solid-state reactions of gadolinium oxide and ammonium dihydrogen phosphateen_US
dc.typeArticleen_US

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