Calculation of the free energies for the solid phases of ammonium halides
Yükleniyor...
Dosyalar
Tarih
2007
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Taylor & Francis Ltd
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
Using mean field theory, we calculate the free energies of the solid phases of ammonium halides. The temperature and pressure dependences of the free energies are obtained using experimental phase diagrams of the ammonium halides. From these dependences, we calculate numerically the specific heat as a function of temperature for the solid I-liquid, solid II-liquid and solid I-solid II transitions in the ammonium halides, in particular for NH4Cl. The critical behaviour of some other thermodynamic quantities is also predicted from the mean field theory.
Açıklama
Anahtar Kelimeler
Ammonium halides
Kaynak
Philosophical Magazine
WoS Q Değeri
Q1
Scopus Q Değeri
Q3
Cilt
87
Sayı
16
