Photochemical synthesis and identification of tetracarbonyl-bis(olefin)metal(0) complexes of group VI B elements

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dc.authorid0000-0002-7585-0136
dc.authorid0000-0002-7585-0136
dc.contributor.authorMorkan, İzzet Amour
dc.contributor.authorUztetik-Morkan, Ayşe
dc.date.accessioned2021-06-23T18:54:55Z
dc.date.available2021-06-23T18:54:55Z
dc.date.issued2000
dc.departmentBAİBÜ, Fen Edebiyat Fakültesi, Kimya Bölümüen_US
dc.description.abstractPhotolysis of hexacarbonyl metal(0) or tetracarbonyl-bis(1,3-butadiene)metal(0) (metal: chromium, molybdenum, tungsten) in the presence of tetracyanoethylene, TCNE, or fumaronitrile , FN, at room temperature yields trans-bis(?2-tetracyano-ethylene)tetracarbonyl-chromium(0) (1), -molybdenum(0) (2), -tungsten(0) (3) and trans-bis(fumaronitrile)tetracarbonyl-chromium(0) (4), -tungsten(0) (5) complexes. The complexes were purified by chromatography and recrystallization and characterized by IR , 1H, 13C NMR and mass spectroscopies. It is shown that two tetracyanoethylene ligands are symmetrically bonded to the M(CO)4 moiety through their carbon-carbon double bond in the form of ?2-TCNE . The two fumaronitrile ligands are bonded to the central atom through their nitrogen atoms. The spectral data are discussed in terms of metal -? ligand ?-interaction.en_US
dc.description.sponsorshipAbant Izzet Baysal Üniversitesi, AIBÜ: AFP 99.03.03.51en_US
dc.description.sponsorshipThis work was supported by the research project fon-dation of AIBÜ (AFP 99.03.03.51) and the Volkswagen-Stiftung.en_US
dc.identifier.doi10.1515/znb-2000-1208
dc.identifier.endpage1156en_US
dc.identifier.issn0932-0776
dc.identifier.issue12en_US
dc.identifier.scopus2-s2.0-0040794294en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage1153en_US
dc.identifier.urihttps://doi.org/10.1515/znb-2000-1208
dc.identifier.urihttps://hdl.handle.net/20.500.12491/4618
dc.identifier.volume55en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorMorkan, İzzet Amour
dc.institutionauthorUztetik-Morkan, Ayşe
dc.language.isoenen_US
dc.publisherVerlag der Zeitschrift fur Naturforschungen_US
dc.relation.ispartofZeitschrift fur Naturforschung - Section B Journal of Chemical Sciencesen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCarbonylen_US
dc.subjectFumaronitrileen_US
dc.subjectTetracyanoethyleneen_US
dc.titlePhotochemical synthesis and identification of tetracarbonyl-bis(olefin)metal(0) complexes of group VI B elementsen_US
dc.typeArticleen_US

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