Crystal structure and thermal decomposition of square planar Ni (II) complexes with ONS type ligands
Yükleniyor...
Dosyalar
Tarih
2010
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Springer/Plenum Publishers
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Similar square planar complexes in the literature were prepared with ONS type N-(2-mercaptophenyl) salicylaldimine and Ni (II). The fourth coordination alongside the tridentate organic ligand was provided by the amine group. The complexes prepared were characterized with Elemental Analyses, IR Spectroscopy and Thermal Analyses. The molecular structures both of the complexes were also determined with X-ray diffraction. The Ni ( II) complex was observed to have a highly distorted square planar structure. The temperature range where the nitrogen containing tridentates ligand left the structure and the corresponding heat changes were compared with those in the literature. The residue after thermal decomposition above 650 degrees C was found to be NiO.
Açıklama
Anahtar Kelimeler
Crystal Structure, Thermal Decomposition, Ni Complexes, ONS Type Ligand
Kaynak
Journal Of Chemical Crystallography
WoS Q Değeri
Q4
Scopus Q Değeri
Q4
Cilt
40
Sayı
9
