A new zwitterionic electrochromatographic stationary phase based on poly(3-chloro-2-hydroxypropyl methacrylate-co-ethylene dimethacrylate) reactive monolith

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dc.authorid0000-0002-7692-0423en_US
dc.contributor.authorAydoğan, Cemil
dc.contributor.authorÇelebi, Bekir
dc.contributor.authorBayraktar, Aslıhan
dc.contributor.authorYılmaz, Fatma
dc.contributor.authorDenizli, Adil
dc.date.accessioned2021-06-23T19:35:42Z
dc.date.available2021-06-23T19:35:42Z
dc.date.issued2014
dc.departmentBAİBÜ, Gerede Meslek Yüksekokulu, Kimya Ve Kimyasal İşleme Teknolojileri Bölümüen_US
dc.description.abstractA new reactive monolith, poly(3-chloro-2-hydroxypropyl methacrylate-co-ethylene dimethacrylate), poly(HPMA-Cl-co-EDMA) was synthesized and post-functionalized by taurine (2-aminoethane sulfonic acid) to obtain a zwitterionic stationary phase for capillary electrochromatography. The new stationary phase contained charged groups such as secondary amine providing anodic electroosmotic flow and sulfonic acid groups providing cathodic electroosmotic flow. Hence, the capillary electrochromatography separations with the new zwitterionic monolith were performed with either anodic or cathodic electroosmotic flow. The electrochromatographic separation of alkylbenzenes and phenols was successfully performed. The zwitterionic monolith also allowed the separation of nucleosides using only electrokinetic mode. Theoretical plate numbers up to similar to 10(5) plates/m were achieved. Our study is the first report based on poly(HPMA-Cl-co-EDMA) reactive monolith post-functionalized with a zwitterionic ligand allowing to operate in both anodic and cathodic electroosmotic flow modes. Copyright (C) 2014 John Wiley & Sons, Ltd.en_US
dc.identifier.doi10.1002/pat.3285
dc.identifier.endpage783en_US
dc.identifier.issn1042-7147
dc.identifier.issn1099-1581
dc.identifier.issue8en_US
dc.identifier.scopus2-s2.0-84904418616en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage777en_US
dc.identifier.urihttps://doi.org/10.1002/pat.3285
dc.identifier.urihttps://hdl.handle.net/20.500.12491/7849
dc.identifier.volume25en_US
dc.identifier.wosWOS:000340087800002en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorYılmaz, Fatma
dc.language.isoenen_US
dc.publisherWiley-Blackwellen_US
dc.relation.ispartofPolymers For Advanced Technologiesen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCapillary Electrochromatographyen_US
dc.subjectMonolithen_US
dc.subjectEthylene Dimethacrylateen_US
dc.subjectZwitterionicen_US
dc.subjectNucleosideen_US
dc.titleA new zwitterionic electrochromatographic stationary phase based on poly(3-chloro-2-hydroxypropyl methacrylate-co-ethylene dimethacrylate) reactive monolithen_US
dc.typeArticleen_US

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