Atakol, OrhanBoca, RomanErcan, İsmailErcan, FilizFuess, HartmutHaase, WolfgangHerchel, Radovan2021-06-232021-06-2320060009-26141873-4448https://doi.org/10.1016/j.cplett.2006.03.067https://hdl.handle.net/20.500.12491/5891A tetradentate ligand, abbr. L2- =dmSALPD(2-) = N,N'-bis(sahcylidene)-1,3-propanediaminato dianion, has been complexed with metal ions in the presence of dimethylformamide (dmf) and nitrite anion. As a result, trinuclear molecular complexes of the type [M-II- {Ni(NO2(L2-)(dmf)}(2)], where M-II = Mn(II), Co(II) and Ni(II) were obtained. The magnetic susceptibility and magnetization data were treated simultaneously during the fitting procedure. In addition to the isotropic exchange, the zero-field splitting parameters D-A were added to the spin Hamiltonian. An anti-ferromagnetic interaction was found in all complexes and the single ion magnetic anisotropy parameter for the Ni(II) peripheral centers adopt considerable values.eninfo:eu-repo/semantics/closedAccessMagnetic PropertiesTrinuclearNickel CompoundsFerromagnetismArticle10.1016/j.cplett.2006.03.0674231-3192196WOS:000237689700039Q2