Aksu, MecitDurmuş, SefaSarı, MusaEmregül, KaanSvoboda, I.2021-06-232021-06-2320071388-6150https://doi.org/10.1007/s10973-006-7729-5https://hdl.handle.net/20.500.12491/600032nd Workshop on Heterogeneous Equilibria between Phases (JEEP 2006) -- MAR 30-31, 2006 -- Univ Rouen, Rouen, FRANCEN,N'-bis(salicylidene)-1,3-propanediamine (LH2), N,N'-bis(salicylidene)-2,2'-dimethyl-1,3-propanediamine (LDMH2), N,N'-bis(salicylidene)-2-hydroxy-1,3-propanediamine (LOH3), N,N'-bis(2-hydroxyacetophenylidene)-1,3-propanediamine (LACH(2)) and N,N'-bis(2-hydroxyacetophenone)-2,2'-dimethyl-1,3-propanediamine (LACDMH(2)) were synthesized and reduced to their phenol-amine form in alcoholic media using NaBH4 ((LH2)-H-H, (LDMH2)-H-H, (LOH2)-H-H, LAC(H)H(2) and LACDM(H)H(2)). Heterodinuclear complexes were synthesized using Ni(II), Zn(II) and Cd(II) salts, according to the template method in DMF media. The complex structures were analyzed using elemental analysis, IR spectroscopy, and thermogravimetry. Suitable crystals of only one complex were obtained and its structure determined using X-ray diffraction, NiLAC(H)center dot CdBr2 center dot DMF2, space group orthorhombic, Pbca, a=20.249, b=14.881, c=20.565 angstrom and Z=8. The heterodinuclear complexes were seen to be of [Ni center dot ligand center dot MX2 center dot DMF2] structure (ligand=LH2-, LDMH2-, LOHH2-, LAC(H2-), LACDM(H2-), M=Zn-II, Cd-II, X=Br-, I-). Thermogravimetric analysis showed irreversible bond breakage of the coordinatively bonded DMF molecules followed by decomposition at this temperature.eninfo:eu-repo/semantics/closedAccessCrystal StructureHeterodinuclear ComplexesONNO type Schiff BasesThermal AnalysisConference Object10.1007/s10973-006-7729-59025415472-s2.0-36849032798Q1WOS:000251088600036Q3