Tanyeli, CihangirÖzdemirhan, Devrim2021-06-232021-06-2320050040-4020https://doi.org/10.1016/j.tet.2005.06.031https://hdl.handle.net/20.500.12491/5688The Manganese(III) -based regioselective alpha'-keto radical generation of unsaturated ketones is a versatile synthetic procedure with broad applicability. The generated alpha'-keto radical slowly creates a metal enolate in a solvent at reflux. The resultant metal enolate affords the corresponding alpha'-allylated alpha,beta-unsaturated ketones in good yields. This method is the first example of the metal mediated regioselective alpha'-allylation of alpha,beta-unsaturated ketones. The ketones that have alpha or beta-alkoxy groups also work efficiently.eninfo:eu-repo/semantics/closedAccessEnonesManganese and CompoundsAllylationArticle10.1016/j.tet.2005.06.0316134821282172-s2.0-22544443924Q2WOS:000230982500015Q2