Ercan, FilizAteş, Meltem B.Ercan, İsmailDurmuş, SefaAtakol, Orhan2021-06-232021-06-2320040232-13001521-4079https://doi.org/10.1002/crat.200310212https://hdl.handle.net/20.500.12491/5604The two linear hetero-trinuclear metallic complexes with Cu2+, Ni2+ and Zn2+ ions, [CuNi2 {(CHO2)(SALPD)[(CH3)(2)NCHO]}(2)],(I) and [ZnNi2{(CHO2)(SALPD)[(CH3)(2)NCHO]}(2)],(II), form crystals which belong to the monoclinic system, space group P2(1)/c, with unit cell dimensions a = 10.537(4), b = 16.612(5), c = 13.837(3) Angstrom, beta = 111.09(5)degrees, V = 2259.8(12) Angstrom(3) in (II) and a = 10.525(4), b = 16.658(5), c = 13.826(3)Angstrom, beta = 111.11(5)degrees,V = 2261.4(8) Angstrom(3) in (II), respectively. The coordinations around the M (Ni2+, Cu2+, Zn2+) ions in the title complexes are distorted octahedrals. The stereochemistries of the bridge ligands, linking to the metal ions each other, are changed between Ni...M (Cu2+, Zn2+) distances. The Ni...M (Cu2+, Zn2+) distances are 3.0469(13) and 3.0645(14), respectively. (C) 2004 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.eninfo:eu-repo/semantics/closedAccessTrinuclear Metallic ComplexesSchiff BasesCrystal StructuresArticle10.1002/crat.2003102123954704762-s2.0-2942552319Q3WOS:000221584000014Q3