Sezer, SerdarÖzdemirhan, DevrimŞahin, ErtanTanyeli, Cihangir2021-06-232021-06-2320060957-4166https://doi.org/10.1016/j.tetasy.2006.11.012https://hdl.handle.net/20.500.12491/5806An intramolecular Pauson-Khand reaction of enynes derived from homoallyl and homopropargyl alcohols is described. 2-Furyl substituted homoallyl and homopropargyl alcohols are easily and efficiently resolved through enzymatic resolution in a high ee (93-99%) with a known stereochemistry. Each enantiomerically enriched enyne affords the conformationally most stable diastereomeric cyclopenta[c]pyran ring system.eninfo:eu-repo/semantics/closedAccessConformational ControlStereochemistryHomopropargylIntramolecularConformational control on remote stereochemistry in the intramolecular pauson-khand reactions of enynes tethered to homoallyl and homopropargyl alcoholsArticle10.1016/j.tetasy.2006.11.0121721298129862-s2.0-33845192880N/AWOS:000243270600006Q2