Rheological study of galactomannan depolymerisation at elevated temperatures: Effect of varying pH and addition of antioxidants

Yükleniyor...
Küçük Resim

Tarih

2010

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

Elsevier Sci Ltd

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

Guar gum (GC) and locust bean gum (LBG) are neutral and should not be expected to change viscosity at different pH values. However, heat treatment at 100 degrees C within the range of pH values 5.0-9.0 did show significant differences in viscosity. Lowest viscosity and therefore probable maximum degradation was found at pH 7.0 which is indicative of free radical attack being optimum at this pH. Antioxidants, sodium sulphite (SS) and propyl gallate (PG), added at 1000 and 500 ppm, respectively, provide both gums with stability when subjected to temperature treatments up to 121 degrees C. This also supports the proposal that it is the action of free radicals at higher temperatures that causes thermal degradation. LBG shows a better conservation of viscosity than CC, on addition of antioxidants, suggesting that the protective effect of its intermolecular associations is further enhanced by the antioxidants. (C) 2010 Elsevier Ltd. All rights reserved.

Açıklama

Anahtar Kelimeler

Galactomannans, Depolymerisation, Thermal Degradation, pH, Antioxidant, Intermolecular Associations

Kaynak

Carbohydrate Polymers

WoS Q Değeri

Q1

Scopus Q Değeri

Q1

Cilt

81

Sayı

3

Künye