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Öğe Co-pyrolysis performances, synergistic mechanisms, and products of textile dyeing sludge and medical plastic wastes(Elsevier, 2021) Ding, Ziyi; Liu, Jingyong; Chen, Huashan; Huang, Shengzheng; Evrendilek, Fatih; He, YaoThis study aimed to quantify the co-pyrolysis of textile dyeing sludge (TDS) and the two medical plastic wastes of syringes (SY) and medical bottles (MB) in terms of their performances, synergistic mechanisms, and products. The pyrolysis of polyolefin plastics with its high calorific value and low ash content can offset the poor monopyrolytic performance of TDS. The synergistic mechanisms occurred mainly in the range of 400-550 degrees C. The addition of 10% SY or MB achieved the best co-pyrolysis performance with the lowest activation energy. The co-pyrolysis increased the contents of CH4 and C-H but reduced CO2 emission. The co-pyrolysis released more fatty hydrocarbons, alcohols, and cyclic hydrocarbon during but reduced the yields of ethers and furans, through the synergistic mechanisms. The addition of the polyolefin plastics made the micro surface particles of chars smaller and looser. Our results can benefit energy utilization, pollution control, and optimal operational conditions for the industrial thermochemical conversions of hazardous wastes. (C) 2021 Elsevier B.V. All rights reserved.Öğe Co-thermal conversion, atmosphere, and blend type controls over heavy metals in biochars and bottom slags of textile dyeing sludge and durian shell(Elsevier Sci Ltd, 2023) Liu, Hui; Chen, Xi; Wei, Xipeng; Chen, Zhibin; Yuan, Haoran; Evrendilek, Fatih; Huang, ShengzhengThe co-thermal conversions of textile dyeing sludge ((TDS) with biomass may be turned into a feasible and green technology to valorize energy and products, but the transformation behavior of heavy metals remains unclear. This study aimed to quantify the migrations and distributions of HMs in biochars and bottom slags and their environmental risks in response to the co-pyrolysis and co-combustion of durian shell (DS) and TDS, atmosphere type, blend ratio, and temperature. The co-combustion interaction of DS and TDS raised the residual HM contents of the bottom slag. Co-pyrolysis reduces the environmental risks of HMs of the TDS, and the effect of CO2 atmosphere is better. In 80N(2)20O(2), Cr, Zn, and Cu in the TDS bottom slag had the highest leaching toxicity concentrations at 900 degrees C. At 800 degrees C, the leaching toxicity concentrations of HMs were Cr > Cu > Zn > Mn in TDS. The O-2 concentration and atmosphere type did not significantly affect the HM morphology and transformation. K increased the temperature of converting solid-phase Ni to slag-phase NiO in DS sample and affected the transformation temperature and strength of Ni, Zn, and Pb in other sample at the high temperature. The combined results of all the three optimizations of HM contents, forms, and risks pointed to add 50 % DS in the N-2 atmosphere and add 50 % DS in 50N(2)50O(2) and 80CO(2)20O(2) atmospheres as the optimal co-pyrolysis/combustion settings, respectively.Öğe Converting and valorizing heavy metal-laden post-harvest hyperaccumulator (Pteris vittate L.) into biofuel via acid-pretreated pyrolysis and gasification(Elsevier Science SA, 2023) Huang, Shengzheng; Liu, Jingyong; Chen, Siqi; Wang, Jin; Chen, Zhibin; Evrendilek, FatihNot only should post-harvest hyperaccumulators rich in heavy metals (HMs) be properly disposed to avoid secondary HMs pollution, but also they should be valorized to enhance circular economy. This study aimed to characterize how As-hyperaccumulator (Pteris vittate L.) (PV) pretreated with HCl or H3PO4 affected its physi-cochemical, HMs, decomposition, and volatile characteristics. The HCl-pretreated PV retained its original main components, physical properties, and chemical structures but introduced Cl to carbon chain, induced O loss, increased C content, and removed most minerals, in particular, alkali/alkaline earth metals. The favorable py-rolysis and gasification behaviors of PV were maintained via the HCl-pretreated PV, with the raised and nar-rowed temperature range of mass loss but with the increased energy demand for the decomposition. Compared with PV (276.74 kJ/mol), 5% HCl-pretreated PV reduced activation energy of its pyrolysis (260.62 kJ/mol). The H3PO4 pretreatment destroyed carbon chain, loaded phosphorus oxygen group, and removed more organics and minerals in PV than did the HCl-pretreated PV. This in turn allowed for an earlier start and finish of devolati-lization stage, an easier breaking of potential energy barrier, and improvement of reaction favorability. Unlike the two atmospheres, the acid pretreatments changed the temperature dependency of volatile products during the main reaction-temperature range. The volatile products which released from the pyrolysis and gasification at the temperature of maximum mass loss peak or 350 degrees C were collected. HCl-pretreated PV reduced the formation of ring-opening products, while H3PO4-pretreated PV emitted more aromatic compounds and selectively generated ketone, such as levoglucanone. More HMs were dissolved with the increased acid concentration, with HMs in HCl-pretreated PV being at a higher leaching concentration than those in the other treatments. H3PO4- pretreated PV retained As, Cd, and Pb at a low leachable rate. The best joint optimization was achieved with the combined settings of 5% HCl-pretreated PV or 10% H3PO4-pretreated PV at 10 degrees C/min in the N2 atmosphere. Overall, findings provide new insights into how to best manage and valorize post-harvest and HM-laden hyperaccumulators.Öğe Dynamic, synergistic, and optimal emissions and kinetics of volatiles during co-pyrolysis of soil remediation plants with kaolin/modified kaolin(Elsevier Science Sa, 2024) Chen, Zhibin; Li, Weijie; Huang, Shengzheng; Zhuang, Ping; Jia, Dajie; Evrendilek, Fatih; Zhong, ShengThe post-harvest disposal of soil remediation plants (SRPs) needs to be eco-friendly for remediation techniques to be sustainable. Incorporating Al/Si-based materials as additives may prove to be an effective method for stabilizing heavy metals during the pyrolysis of Zn/Cd-enriched SRPs. Based on the coupling of thermogravimetry - Fourier-transform infrared spectrometry - mass spectrometry - two-dimensional correlation spectrum analyses (TG-FTIR-MS-2D-COS) and Gaussian modeling, this study aimed to quantify and unveil dynamic, synergistic, and optimal emissions and kinetics of volatile components in response to the co-pyrolysis of Pfaffia glomerata (PG) with kaolin (K) or modified kaolin (KH). The kinetic mechanism of the thermal decomposition stage of volatile components was best accounted for by the diffusion model (100-315 degrees C) and reaction order model (315-600 degrees C).The Al-OH group in K enhanced the evolution and emission of CO2, H2O, and CH4. PG mixed with 10 % K (PK91) reduced the average activation energy value of PG from 217.90 to 196.44 kJ/mol. Compared with K, KH demonstrated superior thermal stability and controlled the cleavage of carbonyl, ether, carboxyl, and methyl groups, thus reducing gaseous pollution. Specifically, PG mixed with 20 % KH (PKH82) minimized the mass loss of PG biochar by 112.81 %, while PG mixed with 10 % KH (PKH91) reduced the E-a value of PG to 155.91 kJ/mol. The sequential temperature dependency of volatiles in PG, identified through two-dimensional correlation spectroscopy, was altered by both K and KH. Given artificial neural network-based simulations, the simultaneously optimized reduction in total volatile emission and fuel mass was achieved with PKH91 but diminished with the rising temperature. These insights contribute to optimizing energy and controlling air pollution during the co-pyrolysis of SRPs with Al/Si-based materials.Öğe Efficiency, by-product valorization, and pollution control of co-pyrolysis of textile dyeing sludge and waste solid adsorbents: Their atmosphere, temperature, and blend ratio dependencies(Elseiver, 2022) Zou, Huihuang; Huang, Shengzheng; Ren, Mingzhong; Liu, Jingyong; Evrendilek, Fatih; Xie, WumingThis study aimed to quantify the co-pyrolytic synergistic effects of textile dyeing sludge (TDS) and waste biochar (WBC) for an optimal utilization of secondary resources and to mitigate environmental pollution and waste volume. TDS and WBC had a strong synergistic effect between 800 and 900 degrees C in the CO2-assisted atmosphere. With the increased TDS fraction, NH3 emission fell significantly regardless of the atmosphere type. The CO2 atmosphere changed Sin TDS char and released SO2 in the range of 800-1000 degrees C. With the temperature rise, an unstable N structure turned into a more stable heterocyclic N structure in the CO2 and N-2 atmospheres. Regardless of the atmosphere type and temperature, the C-containing functional groups in co-pyrolytic biochar existed mainly as C-C/C-H. In the CO2 atmosphere, inorganic S, aliphatic S, and thiophene S in the co-pyrolytic biochar disappeared and became more stable sulfones. The co-pyrolysis inhibited the formation of S-containing compounds. The retention ability of the copyrolytic biochar peaked for most of the heavy metals in the N-2 atmosphere but was better for Pb and Zn in the CO2 than N-2 atmosphere. Simultaneous optimization showed the co-pyrolysis of 10% TDS and 90% WBC at above 950 degrees C in the N-2-CO2 or CO2 atmosphere as the optimal operational settings combined.Öğe Energetic, bio-oil, biochar, and ash performances of co-pyrolysis-gasification of textile dyeing sludge and Chinese medicine residues in response to K 2 CO 3, atmosphere type, blend ratio, and temperature(Science Press, 2024) Zhang, Gang; Chen, Zhiyun; Chen, Tao; Jiang, Shaojun; Eurendilek, Fatih; Huang, Shengzheng; Tang, XiaojieHazardous waste stream needs to be managed so as not to exceed stock- and rate-limited properties of its recipient ecosystems. The co-pyrolysis of Chinese medicine residue (CMR) and textile dyeing sludge (TDS) and its bio-oil, biochar, and ash quality and quantity were characterized as a function of the immersion of K 2 CO 3 , atmosphere type, blend ratio, and temperature. Compared to the mono-pyrolysis of TDS, its co-pyrolysis performance with CMR (the comprehensive performance index (CPI)) significantly improved by 33.9% in the N 2 atmosphere and 33.2% in the CO 2 atmosphere. The impregnation catalyzed the co-pyrolysis at 370 degrees C, reduced its activation energy by 77.3 kJ/mol in the N 2 atmosphere and 134.6 kJ/mol in the CO 2 atmosphere, and enriched the degree of coke gasification by 44.25% in the CO 2 atmosphere. The impregnation increased the decomposition rate of the co-pyrolysis by weakening the bond energy of fatty side chains and bridge bonds, its catalytic and secondary products, and its bio-oil yield by 66.19%. Its bio-oils mainly contained olefins, aromatic structural substances, and alcohols. The immersion of K 2 CO 3 improved the aromaticity of the coÖğe Energetic, bio-oil, biochar, and ash performances of co-pyrolysis-gasification of textile dyeing sludge and Chinese medicine residues in response to K2CO3, atmosphere type, blend ratio, and temperature(Chinese Academy of Sciences, 2024) Zhang, Gang; Chen, Zhiyun; Chen, Tao; Jiang, Shaojun; Evrendilek, Fatih; Huang, Shengzheng; Tang, XiaojieHazardous waste stream needs to be managed so as not to exceed stock- and rate-limited properties of its recipient ecosystems. The co-pyrolysis of Chinese medicine residue (CMR) and textile dyeing sludge (TDS) and its bio-oil, biochar, and ash quality and quantity were characterized as a function of the immersion of K2CO3, atmosphere type, blend ratio, and temperature. Compared to the mono-pyrolysis of TDS, its co-pyrolysis performance with CMR (the comprehensive performance index (CPI)) significantly improved by 33.9% in the N2 atmosphere and 33.2% in the CO2 atmosphere. The impregnation catalyzed the co-pyrolysis at 370°C, reduced its activation energy by 77.3 kJ/mol in the N2 atmosphere and 134.6 kJ/mol in the CO2 atmosphere, and enriched the degree of coke gasification by 44.25% in the CO2 atmosphere. The impregnation increased the decomposition rate of the co-pyrolysis by weakening the bond energy of fatty side chains and bridge bonds, its catalytic and secondary products, and its bio-oil yield by 66.19%. Its bio-oils mainly contained olefins, aromatic structural substances, and alcohols. The immersion of K2CO3 improved the aromaticity of the co-pyrolytic biochars and reduced the contact between K and Si which made it convenient for Mg to react with SiO2 to form magnesium-silicate. The co-pyrolytic biochar surfaces mainly included -OH, -CH2, C=C, and Si-O-Si. The main phases in the co-pyrolytic ash included Ca5(PO4)3(OH), Al2O3, and magnesium-silicate. © 2022Öğe Optimizing co-combustion synergy of soil remediation biomass and pulverized coal toward energetic and gas-to-ash pollution controls(Elsevier, 2023) Chen, Zhibin; Chen, Zhiliang; Liu, Jingyong; Zhuang, Ping; Evrendilek, Fatih; Huang, Shengzheng; Chen, Tao; Xie, Wuming; He, Yao; Sun, ShuiyuThe co-combustion synergy of post-phytoremediation biomass may be optimized to cultivate a variety of benefits from re ducing dependence on fossil fuels to stabilizing heavy metals in a small quantity of ash. This study characterized the thermo kinetic parameters, gas-to-ash products, and energetically and environmentally optimal conditions for the co-combustions of aboveground (PG-A) and belowground (PG-B) biomass of Pfaffia glomerata (PG) with pulverized coal (PC). The mono combustions of PG-A and PG-B involved the decompositions of cellulose and hemicellulose in the range of 162–400 °C and of lignin in the range of 400–600 °C. PG improved the combustion performance of PC, with the blends of 30 % PG A and 70 % (PAC37) and 10 % PG-B and 90 % PC (PBC19) exhibiting the strongest synergy. Both PG-A and PG-B interacted with PC in the range of 160–440 °C, while PC positively affected PG in the range of 440–600 °C. PC decreased the apparent activation energy (Eα) of PG, with PBC19 having the lowest Eα value (107.85 kJ/mol). The reaction order models (Fn) best elucidated the co-combustion mechanisms of the main stages. Adding >50 % PC reduced the alkali metal content of PG, prevented the slagging and fouling depositions, and mitigated the Cd and Zn leaching toxicity. The functional groups, vol atiles, and N- and S-containing gases fell with PAC37 and PBC19, while CO2 emission rose. Energetically and environmen tally multiple objectives for the operational conditions were optimized via artificial neural networks. Our study presents controls over the co-circularity and co-combustion of the soil remediation plant and coal
